| New insight into the mechanism of LiPO2F2 on the interface of high-voltage cathode LiNi0.5Mn1.5O4 with truncated octahedral structure | |
Zhao, Dongni1 ; Song, Sainan3; Ye, Xiushen2; Wang, Peng1; Wang, Jie1; Wei, Yuan1; Li, Chunlei1; Mao, Liping1; Zhang, Haiming2; Li, Shiyou1
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| 2019-10-15 | |
| 发表期刊 | APPLIED SURFACE SCIENCE
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| ISSN | 0169-4332 |
| 卷号 | 491页码:595-606 |
| 摘要 | The development of high energy density material is of great importance and urgency for new generation of energy storage system. However, electrolyte formula for high voltage system remains a challenge. The use of various functional additives gives rise to the complexity of electrolyte system and hinders completely understanding of the action mechanism of additives. Herein, we report the adaptability and mechanism of a single additive LiPO2F2 added in the conventional LiPF6-based electrolyte system. The resulting conclusion displays a notable improvement in the cycling stability for 5 V-class cathode LiNi0.5Mn1.5O4, the capacity retention increase from 85.76% to 95.92%. It is comforting that the rate performance is not reduced due to the increase in cycle stability, and it also shows good advantages in terms of high rate and reversibility. Meanwhile, detailed analysis about interface mechanism for LiPO2F2 by the surface testing (SEM, TEM and XPS) give the direct characterizations. Common ion effect of the decomposition product Li3PO4 from additive is probed from the above characterization and combined with DFT calculations and some clever experiments to prove the positive effect of additives. The findings obtained from this work may provide a useful guidance for the research on electrolyte formulation for high voltage system. |
| 关键词 | LiPO2F2 LiNi0.5Mn1.5O4 Electrolyte additive Common ion effect Interface film |
| DOI | 10.1016/j.apsusc.2019.06.146 |
| 收录类别 | SCI |
| 语种 | 英语 |
| 资助项目 | Science and Technology Project for Gansu Province[18JR3RA160] |
| WOS研究方向 | Chemistry ; Materials Science ; Physics |
| WOS类目 | Chemistry, Physical ; Materials Science, Coatings & Films ; Physics, Applied ; Physics, Condensed Matter |
| WOS记录号 | WOS:000479082900067 |
| 出版者 | ELSEVIER |
| 引用统计 | |
| 文献类型 | 期刊论文 |
| 条目标识符 | https://ir.lut.edu.cn/handle/2XXMBERH/31504 |
| 专题 | 石油化工学院 |
| 通讯作者 | Li, Shiyou |
| 作者单位 | 1.Lanzhou Univ Technol, Coll Petrochem Technol, 36 Pengjiaping Rd, Lanzhou 730050, Gansu, Peoples R China 2.Chinese Acad Sci, Qinghai Inst Salt Lakes, CAS Key Lab Comprehens & Highly Efficient Utiliza, Xining 810008, Qinghai, Peoples R China 3.Petrochina, Lanzhou Petrochem Res Ctr, Lanzhou 730060, Gansu, Peoples R China |
| 第一作者单位 | 石油化工学院 |
| 通讯作者单位 | 石油化工学院 |
| 第一作者的第一单位 | 石油化工学院 |
| 推荐引用方式 GB/T 7714 | Zhao, Dongni,Song, Sainan,Ye, Xiushen,et al. New insight into the mechanism of LiPO2F2 on the interface of high-voltage cathode LiNi0.5Mn1.5O4 with truncated octahedral structure[J]. APPLIED SURFACE SCIENCE,2019,491:595-606. |
| APA | Zhao, Dongni.,Song, Sainan.,Ye, Xiushen.,Wang, Peng.,Wang, Jie.,...&Li, Shiyou.(2019).New insight into the mechanism of LiPO2F2 on the interface of high-voltage cathode LiNi0.5Mn1.5O4 with truncated octahedral structure.APPLIED SURFACE SCIENCE,491,595-606. |
| MLA | Zhao, Dongni,et al."New insight into the mechanism of LiPO2F2 on the interface of high-voltage cathode LiNi0.5Mn1.5O4 with truncated octahedral structure".APPLIED SURFACE SCIENCE 491(2019):595-606. |
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