| Sonocatalytic activity of LuFeO_3 crystallites synthesized via a hydrothermal route |
| Zhou Ming; Yang Hua; Xian Tao; Yang Yang; Zhang Yunchuan
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| 2015
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发表期刊 | 催化学报
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ISSN | 0253-9837
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卷号 | 36期号:11页码:1987-1994 |
摘要 | LuFeO_3 crystallites of different sizes and morphologies were synthesized via a hydrothermal route. The sonocatalytic properties of the as-synthesized samples were investigated by degrading various organic dyes, including acid orange 7 (AO7), rhodamine B (RhB), methyl orange (MO), and methylene blue (MB), under ultrasonic irradiation, revealing that they exhibit excellent sonocatalytic activity toward the degradation of these dyes. Particularly, the synthesized bar-like particles with lengths of ~3 mum and widths of ~1 mum have the highest sonocatalytic activity, and the degradation percentage of AO7 reaches 89% after 30 min of sonocatalysis. The effects of inorganic anions such as Cl~-, NO_3~-, SO_4~(2-), PO_4~(3-), and HCO_3~- on the sonocatalysis efficiency were investigated. Hydroxyl radicals (?OH) detected by fluorimetry using terephthalic acid as a probe molecule were found to be produced over the ultrasonic-irradiated LuFeO_3 particles. The addition of ethanol, which acts as a?OH scavenger, leads to quenching of ?OH radicals and a simultaneous decrease in the dye degradation. This suggests that ?OH is the dominant active species responsible for the dye degradation. |
关键词 | Lutetium orthoferrite
Hydrothermal synthesis
Sonocatalytic activity
Hydroxyl radical
Inorganic anion
Degradation of organic dyes
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收录类别 | CSCD
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语种 | 英语
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WOS研究方向 | Chemistry
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WOS类目 | CHEMISTRY MULTIDISCIPLINARY
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CSCD记录号 | CSCD:5552117
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引用统计 | |
文献类型 | 期刊论文
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条目标识符 | https://ir.lut.edu.cn/handle/2XXMBERH/70991
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专题 | 理学院
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作者单位 | School of Science, Lanzhou University of Technology, Lanzhou, Gansu 730050, China
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第一作者单位 | 兰州理工大学
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第一作者的第一单位 | 兰州理工大学
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推荐引用方式 GB/T 7714 |
Zhou Ming,Yang Hua,Xian Tao,et al. Sonocatalytic activity of LuFeO_3 crystallites synthesized via a hydrothermal route[J]. 催化学报,2015,36(11):1987-1994.
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APA |
Zhou Ming,Yang Hua,Xian Tao,Yang Yang,&Zhang Yunchuan.(2015).Sonocatalytic activity of LuFeO_3 crystallites synthesized via a hydrothermal route.催化学报,36(11),1987-1994.
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MLA |
Zhou Ming,et al."Sonocatalytic activity of LuFeO_3 crystallites synthesized via a hydrothermal route".催化学报 36.11(2015):1987-1994.
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