Highly efficient solar steam generation of bilayered ultralight aerogels based on N-rich conjugated microporous polymers nanotubes
Zhu, Zhaoqi; Mu, Peng; Fan, Yukang; Bai, Wei; Zhang, Zheng; Sun, Hanxue; Liang, Weidong; Li, An
2020-03-05
发表期刊EUROPEAN POLYMER JOURNAL
ISSN0014-3057
卷号126
摘要

Solar steam generation is one of the most promising and efficient methods to solve freshwater shortage and to treat the wastewater over the world. However, the preparation of the solar steam generator with simple preparation process, controlled porous structure, high mechanical strength and energy conversion efficiency is still a challenge. Here, we report a bilayered heterocyclic conjugated microporous polymers aerogels based solar receiver by combination of the one-pot Sonogashira-Hagihara reaction of 2-amino-3,5-dibromopyridine and 1,3,5-triethynylbenzene and spraying the polypyrrole on the surface of the aerogels for the solar steam generation. The as-prepared solar steam generator shows nanotubular structure with high porosity (94%), excellent light absorption (ca. 94%), low thermal conductivity (0.031 W m(-1) k(-1)), rapid water transport performance and superior mechanical strength (0.54 MPa under 75% of strain). Under 1 sun illumination, the conjugated microporous polymers aerogels based solar steam generator achieved a high energy conversion efficiency of 80%. This work may provide a simple and novel way to design and fabricate solar receiver with adjustable structure.

关键词Conjugated microporous polymers Nanotubes Aerogel Solar steam generation
DOI10.1016/j.eurpolymj.2020.109560
收录类别SCI ; SCIE ; EI
语种英语
资助项目National Natural Science Foundation of China[21975113][51663012][51962018] ; Project of Collaborative Innovation Team, Gansu Province, China[052005] ; Innovation and Entrepreneurship Talent Project of Lanzhou[2017-RC -33]
WOS研究方向Polymer Science
WOS类目Polymer Science
WOS记录号WOS:000518871100011
出版者PERGAMON-ELSEVIER SCIENCE LTD
EI入藏号20200708183955
EI主题词Aerogels
EI分类号452.4 Industrial Wastes Treatment and Disposal - 525.5 Energy Conversion Issues - 614.2 Steam Power Plant Equipment and Operation - 641.1 Thermodynamics - 657.1 Solar Energy and Phenomena - 741.1 Light/Optics - 761 Nanotechnology - 801.3 Colloid Chemistry - 815.1.1 Organic Polymers - 931.2 Physical Properties of Gases, Liquids and Solids
来源库WOS
引用统计
被引频次:37[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符https://ir.lut.edu.cn/handle/2XXMBERH/64302
专题石油化工学院
通讯作者Li, An
作者单位Lanzhou Univ Technol, Coll Petrochem Technol, Sch Mat Sci & Engn, Lanzhou 730050, Peoples R China
第一作者单位石油化工学院
通讯作者单位石油化工学院
第一作者的第一单位石油化工学院
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GB/T 7714
Zhu, Zhaoqi,Mu, Peng,Fan, Yukang,et al. Highly efficient solar steam generation of bilayered ultralight aerogels based on N-rich conjugated microporous polymers nanotubes[J]. EUROPEAN POLYMER JOURNAL,2020,126.
APA Zhu, Zhaoqi.,Mu, Peng.,Fan, Yukang.,Bai, Wei.,Zhang, Zheng.,...&Li, An.(2020).Highly efficient solar steam generation of bilayered ultralight aerogels based on N-rich conjugated microporous polymers nanotubes.EUROPEAN POLYMER JOURNAL,126.
MLA Zhu, Zhaoqi,et al."Highly efficient solar steam generation of bilayered ultralight aerogels based on N-rich conjugated microporous polymers nanotubes".EUROPEAN POLYMER JOURNAL 126(2020).
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