Thermodynamic and kinetic studies on harmful algal blooms harvesting by novel etherified cationic straw flocculant
Wu, Haihua1; Chang, Haixing1,2; Zhong, Nianbing3; Tang, Yuting1; Gong, Yuqi1; Wu, Wenbo1; Liu, Jian4; Yin, Taikun5; Li, Gang5; Ho, Shih-Hsin2
2022-10
发表期刊BIORESOURCE TECHNOLOGY
ISSN0960-8524
卷号361
摘要Harmful algal blooms (HABs) are growing threats that cause tens of billion dollars economic loss annually. Aiming at efficient disposal of HABs, a cheap and eco-friendly cationic straw was developed by etherification of wheat straw, which replaced hydroxyl groups on cellulose by quaternary ammonium groups. It endowed the cationic straw with high positive charge and achieved 93.92% of harvesting efficiency by enhancing HABs cells aggregation via charge neutralization. Different from inorganic salts-based flocculants, HABs harvesting by the cationic straw is a spontaneous and exothermic process with negative & UDelta;G and & UDelta;H under all adsorption con-ditions. Thermodynamics and kinetics analysis elucidated that HABs adsorption process by cationic straw were mainly driven by physical forces. Together, cationic straw preparation and HABs harvesting processes were comprehensively optimized with orthogonal experiments. The work may inspire cost-effective HABs disposal and fill knowledge gaps of process nature for HABs harvesting.
关键词Harmful algal blooms Cationic straw Flocculation Thermodynamic Kinetic
DOI10.1016/j.biortech.2022.127737
收录类别SCIE ; EI
语种英语
WOS研究方向Agriculture ; Biotechnology & Applied Microbiology ; Energy & Fuels
WOS类目Agricultural Engineering ; Biotechnology & Applied Microbiology ; Energy & Fuels
WOS记录号WOS:000841484500006
出版者ELSEVIER SCI LTD
EI入藏号20223312563099
EI主题词Kinetics
EI分类号631.1 Fluid Flow, General ; 641.1 Thermodynamics ; 802.3 Chemical Operations ; 911.2 Industrial Economics ; 931 Classical Physics ; Quantum Theory ; Relativity
来源库WOS
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被引频次:9[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符https://ir.lut.edu.cn/handle/2XXMBERH/159853
专题石油化工学院
通讯作者Chang, Haixing
作者单位1.Chongqing Univ Technol, Coll Chem & Chem Engn, Chongqing 400054, Peoples R China;
2.Harbin Inst Technol, Sch Environm, State Key Lab Urban Water Resource & Environm, Harbin 150090, Heilongjiang, Peoples R China;
3.Chongqing Univ Technol, Intelligent Fiber Sensing Technol Chongqing Munici, Chongqing Key Lab Fiber Opt Sensor & Photodetector, Chongqing 400054, Peoples R China;
4.Lanzhou Univ Technol, Coll Petrochem Technol, Lanzhou 730050, Peoples R China;
5.Henan Agr Univ, Coll Mech & Elect Engn, Zhengzhou 450002, Peoples R China
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Wu, Haihua,Chang, Haixing,Zhong, Nianbing,et al. Thermodynamic and kinetic studies on harmful algal blooms harvesting by novel etherified cationic straw flocculant[J]. BIORESOURCE TECHNOLOGY,2022,361.
APA Wu, Haihua.,Chang, Haixing.,Zhong, Nianbing.,Tang, Yuting.,Gong, Yuqi.,...&Ho, Shih-Hsin.(2022).Thermodynamic and kinetic studies on harmful algal blooms harvesting by novel etherified cationic straw flocculant.BIORESOURCE TECHNOLOGY,361.
MLA Wu, Haihua,et al."Thermodynamic and kinetic studies on harmful algal blooms harvesting by novel etherified cationic straw flocculant".BIORESOURCE TECHNOLOGY 361(2022).
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