In-situ fabrication of a phase continuous transition Bismuth iodide/Bismuth niobate heterojunction: Interface regulation and the enhanced photodegradation mechanism
Zhang, Huining1,2,3; Xiao, Yankui1; Tian, Lihong1; Tang, Yuling1; Liu, Xingmao1; Shi, Zhongyu1; Wu, Zhiguo2; Wei, Zhiqiang1
2022-10-01
发表期刊CHEMICAL PHYSICS
ISSN0301-0104
卷号562
摘要A direct Z-scheme bismuth iodide/bismuth niobate (BiOI/BiNbO) heterojunction photocatalysts with a different molar ratio of Bi/Nb were prepared. The structural and photoelectrical properties of these as-prepared samples were investigated, photocatalytic activity and different effect factors were evaluated. The experiment results indicated that the highest RhB degradation efficiency was that of the sample with Bi/Nb = 0.7, bringing a lower interface resistance that facilitate the separation and transportation of photogenerated carrier. Furthermore, active species trapping experiments suggested that center dot OH was the most contributor responsible for the RhB photocatalytic process. The photodegradation mechanism and a reasonable degradation pathway were further proposed by DFT theoretical calculation.
关键词Bismuthiodide Bismuthniobate Interfacestructure RhB Photocatalysis
DOI10.1016/j.chemphys.2022.111644
收录类别SCIE
语种英语
WOS研究方向Chemistry ; Physics
WOS类目Chemistry, Physical ; Physics, Atomic, Molecular & Chemical
WOS记录号WOS:000830884000001
出版者ELSEVIER
来源库WOS
引用统计
被引频次:4[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符https://ir.lut.edu.cn/handle/2XXMBERH/159442
专题土木工程学院
理学院
通讯作者Zhang, Huining
作者单位1.Lanzhou Univ Technol, Sch Civil Engn, Lanzhou 730050, Peoples R China;
2.Gansu Acad Sci, Inst Nanomat Applicat Technol, Lanzhou 730030, Peoples R China;
3.Lanzhou Univ Technol, Sch Civil Engn, Langongping Rd 287, Lanzhou 730050, Peoples R China
第一作者单位兰州理工大学
通讯作者单位兰州理工大学
第一作者的第一单位兰州理工大学
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Zhang, Huining,Xiao, Yankui,Tian, Lihong,et al. In-situ fabrication of a phase continuous transition Bismuth iodide/Bismuth niobate heterojunction: Interface regulation and the enhanced photodegradation mechanism[J]. CHEMICAL PHYSICS,2022,562.
APA Zhang, Huining.,Xiao, Yankui.,Tian, Lihong.,Tang, Yuling.,Liu, Xingmao.,...&Wei, Zhiqiang.(2022).In-situ fabrication of a phase continuous transition Bismuth iodide/Bismuth niobate heterojunction: Interface regulation and the enhanced photodegradation mechanism.CHEMICAL PHYSICS,562.
MLA Zhang, Huining,et al."In-situ fabrication of a phase continuous transition Bismuth iodide/Bismuth niobate heterojunction: Interface regulation and the enhanced photodegradation mechanism".CHEMICAL PHYSICS 562(2022).
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