In-situ fabrication of a phase continuous transition Bismuth iodide/Bismuth niobate heterojunction: Interface regulation and the enhanced photodegradation mechanism | |
Zhang, Huining1,2,3; Xiao, Yankui1; Tian, Lihong1; Tang, Yuling1; Liu, Xingmao1; Shi, Zhongyu1; Wu, Zhiguo2; Wei, Zhiqiang1 | |
2022-10-01 | |
发表期刊 | CHEMICAL PHYSICS |
ISSN | 0301-0104 |
卷号 | 562 |
摘要 | A direct Z-scheme bismuth iodide/bismuth niobate (BiOI/BiNbO) heterojunction photocatalysts with a different molar ratio of Bi/Nb were prepared. The structural and photoelectrical properties of these as-prepared samples were investigated, photocatalytic activity and different effect factors were evaluated. The experiment results indicated that the highest RhB degradation efficiency was that of the sample with Bi/Nb = 0.7, bringing a lower interface resistance that facilitate the separation and transportation of photogenerated carrier. Furthermore, active species trapping experiments suggested that center dot OH was the most contributor responsible for the RhB photocatalytic process. The photodegradation mechanism and a reasonable degradation pathway were further proposed by DFT theoretical calculation. |
关键词 | Bismuthiodide Bismuthniobate Interfacestructure RhB Photocatalysis |
DOI | 10.1016/j.chemphys.2022.111644 |
收录类别 | SCIE |
语种 | 英语 |
WOS研究方向 | Chemistry ; Physics |
WOS类目 | Chemistry, Physical ; Physics, Atomic, Molecular & Chemical |
WOS记录号 | WOS:000830884000001 |
出版者 | ELSEVIER |
来源库 | WOS |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | https://ir.lut.edu.cn/handle/2XXMBERH/159442 |
专题 | 土木工程学院 理学院 |
通讯作者 | Zhang, Huining |
作者单位 | 1.Lanzhou Univ Technol, Sch Civil Engn, Lanzhou 730050, Peoples R China; 2.Gansu Acad Sci, Inst Nanomat Applicat Technol, Lanzhou 730030, Peoples R China; 3.Lanzhou Univ Technol, Sch Civil Engn, Langongping Rd 287, Lanzhou 730050, Peoples R China |
第一作者单位 | 兰州理工大学 |
通讯作者单位 | 兰州理工大学 |
第一作者的第一单位 | 兰州理工大学 |
推荐引用方式 GB/T 7714 | Zhang, Huining,Xiao, Yankui,Tian, Lihong,et al. In-situ fabrication of a phase continuous transition Bismuth iodide/Bismuth niobate heterojunction: Interface regulation and the enhanced photodegradation mechanism[J]. CHEMICAL PHYSICS,2022,562. |
APA | Zhang, Huining.,Xiao, Yankui.,Tian, Lihong.,Tang, Yuling.,Liu, Xingmao.,...&Wei, Zhiqiang.(2022).In-situ fabrication of a phase continuous transition Bismuth iodide/Bismuth niobate heterojunction: Interface regulation and the enhanced photodegradation mechanism.CHEMICAL PHYSICS,562. |
MLA | Zhang, Huining,et al."In-situ fabrication of a phase continuous transition Bismuth iodide/Bismuth niobate heterojunction: Interface regulation and the enhanced photodegradation mechanism".CHEMICAL PHYSICS 562(2022). |
条目包含的文件 | 条目无相关文件。 |
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。
修改评论