Decorating activated carbon: insight to the difference and the storage mechanism of loading NiO and MnO2
Zhang, Ningshuang1,2; Li, Runrun1,2; Ding, Hao1,2; Dong, Hong1,2; Wang, Peng1,2; Wang, Jie1,2; Zhao, Dongni1,2; Li, Shiyou1,2
2022-07
发表期刊Ionics
ISSN0947-7047
卷号28期号:7页码:3571-3581
摘要The application of activated carbon is greatly limited by its low energy density. Here, the angelica herb residue–based activated carbon (AHRAC) materials modified by loading NiO and MnO2 were prepared via a hydrothermal reaction, respectively. The results of structure measurements and electrochemical tests reveal that NiO is more beneficial for improving the specific capacitance (about 678.2 F g−1) and energy density (about 30 Wh kg−1) of AHRAC owing to its unique flower-like morphology and abundant porosity. In addition, combining the density functional theory calculation (DFT), differential pulse voltammetry (DPV), and diffusion coefficient calculation, the difference between AHRAC@NiO and AHRAC@MnO2 was analyzed, which may be ascribed to the larger pseudo-capacitance contribution, bigger diffusion coefficient, and higher adsorption behavior for OH−. In this work, not only a porous carbon with a high specific surface area was prepared, but also the biomass waste was reused. © 2022, The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.
关键词Activated carbon Capacitance Diffusion Manganese oxide Morphology Nickel oxide Porous materials Supercapacitor Voltammetry Carbon material Composites material Density-functional-theory Differential pulse voltammetry Energy density Herb residues Hydrothermal reaction Lower energies Metal-oxide Storage mechanism
DOI10.1007/s11581-022-04593-5
收录类别EI ; SCIE
语种英语
WOS研究方向Chemistry ; Electrochemistry ; Physics
WOS类目Chemistry, Physical ; Electrochemistry ; Physics, Condensed Matter
WOS记录号WOS:000793029100001
出版者Springer Science and Business Media Deutschland GmbH
EI入藏号20221912102732
EI主题词Density functional theory
EI分类号701.1 Electricity: Basic Concepts and Phenomena ; 704.1 Electric Components ; 801.4.1 Electrochemistry ; 804 Chemical Products Generally ; 804.2 Inorganic Compounds ; 922.1 Probability Theory ; 931.2 Physical Properties of Gases, Liquids and Solids ; 931.3 Atomic and Molecular Physics ; 931.4 Quantum Theory ; Quantum Mechanics ; 951 Materials Science
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文献类型期刊论文
条目标识符https://ir.lut.edu.cn/handle/2XXMBERH/159070
专题石油化工学院
通讯作者Li, Shiyou
作者单位1.Lanzhou Univ Technol, Sch Petrochem Technol, Lanzhou 730050, Peoples R China;
2.Gansu Key Lab Low Carbon Energy & Chem Engn, Lanzhou 730050, Peoples R China
第一作者单位兰州理工大学
通讯作者单位兰州理工大学
第一作者的第一单位兰州理工大学
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Zhang, Ningshuang,Li, Runrun,Ding, Hao,et al. Decorating activated carbon: insight to the difference and the storage mechanism of loading NiO and MnO2[J]. Ionics,2022,28(7):3571-3581.
APA Zhang, Ningshuang.,Li, Runrun.,Ding, Hao.,Dong, Hong.,Wang, Peng.,...&Li, Shiyou.(2022).Decorating activated carbon: insight to the difference and the storage mechanism of loading NiO and MnO2.Ionics,28(7),3571-3581.
MLA Zhang, Ningshuang,et al."Decorating activated carbon: insight to the difference and the storage mechanism of loading NiO and MnO2".Ionics 28.7(2022):3571-3581.
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