One-pot synthesis of NiPt core–shell nanoparticles toward efficient oxygen reduction reaction | |
Cong, Yuanyuan1,3; Wang, Haibin1,3; Meng, Fanchao1,3; Dou, Di1,3; Meng, Xiangzhi1,3; Zhao, Qiuping1,3; Cao, Dumeng2,4; Wang, Yi1,3 | |
2022-07 | |
发表期刊 | Journal of Solid State Electrochemistry |
ISSN | 1432-8488 |
卷号 | 26期号:6-7页码:1381-1388 |
摘要 | Creating bimetallic Pt-based nanocrystals with core–shell structures has widely been recognized as the most effective way for improving their electrochemical properties. Herein, a simple one-pot synthesis method is used to prepare Ni1.1Pt nanoparticles (NPs) (~ 5.3 nm) with a nickel (Ni)-rich core and a Pt-rich thin shell (~ 1.0 nm). The Ni1.1Pt/C shows enhanced acid oxygen reduction reaction (ORR) activity with a mass activity (MA) of 661.7 mA mgPt−1 and specific activity (SA) of 1.52 mA cmPt−2, which is 4.3 and 8.4 times that of commercial JM Pt/C, respectively. In addition, Ni1.1Pt/C is also demonstrated to have better ORR stability than JM Pt/C. These excellent properties are contributed to the suitable compressive strain, appropriate electronic effects, and outstanding anti-aggregation of the core–shell structure. © 2022, The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature. |
关键词 | Electrolytic reduction Nanoparticles Oxygen Platinum alloys Shells (structures) Synthesis (chemical) Activity Bimetallics Core shell structure Core-shell nanoparticles Nipt core–shell nanoparticle One-pot synthesis Oxygen reduction reaction Pt nanoparticles Simple++ Synthesis method |
DOI | 10.1007/s10008-022-05175-1 |
收录类别 | EI ; SCIE |
语种 | 英语 |
WOS研究方向 | Electrochemistry |
WOS类目 | Electrochemistry |
WOS记录号 | WOS:000794895600001 |
出版者 | Springer Science and Business Media Deutschland GmbH |
EI入藏号 | 20221712042299 |
EI主题词 | Binary alloys |
EI分类号 | 408.2 Structural Members and Shapes ; 533.1 Ore Treatment ; 547.1 Precious Metals ; 761 Nanotechnology ; 802.2 Chemical Reactions ; 804 Chemical Products Generally ; 933 Solid State Physics |
来源库 | WOS |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | https://ir.lut.edu.cn/handle/2XXMBERH/158500 |
专题 | 石油化工学院 |
通讯作者 | Cao, Dumeng; Wang, Yi |
作者单位 | 1.Lanzhou Univ Technol, Sch Petrochem Technol, Lanzhou 730050, Gansu, Peoples R China; 2.Natl Nickel & Cobalt Adv Mat Engn Res Ctr, Lanzhou 730101, Gansu, Peoples R China; 3.Lanzhou Univ Technol, Key Lab Low Carbon Energy & Chem Engn Gansu Prov, Lanzhou 730050, Gansu, Peoples R China; 4.Lanzhou Jinchuan Technol Pk Co Ltd, Lanzhou 730101, Gansu, Peoples R China |
第一作者单位 | 兰州理工大学 |
通讯作者单位 | 兰州理工大学 |
第一作者的第一单位 | 兰州理工大学 |
推荐引用方式 GB/T 7714 | Cong, Yuanyuan,Wang, Haibin,Meng, Fanchao,et al. One-pot synthesis of NiPt core–shell nanoparticles toward efficient oxygen reduction reaction[J]. Journal of Solid State Electrochemistry,2022,26(6-7):1381-1388. |
APA | Cong, Yuanyuan.,Wang, Haibin.,Meng, Fanchao.,Dou, Di.,Meng, Xiangzhi.,...&Wang, Yi.(2022).One-pot synthesis of NiPt core–shell nanoparticles toward efficient oxygen reduction reaction.Journal of Solid State Electrochemistry,26(6-7),1381-1388. |
MLA | Cong, Yuanyuan,et al."One-pot synthesis of NiPt core–shell nanoparticles toward efficient oxygen reduction reaction".Journal of Solid State Electrochemistry 26.6-7(2022):1381-1388. |
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