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Facile Synthesis of Cobalt Tungstate with Special Defect Structure with Enhanced Optical, Photoluminescence, and Supercapacitive Performances
Gao, Huajing1,2; Tang, Shengnan1; Chen, Xiangyu1; Yu, Chuan1; Wang, Shifa1,3,4; Fang, Leiming4; Yu, Xianlun1; Zhao, Xinxin1; Sun, Guangzhuang1; Yang, Hua2
2021-12
发表期刊RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A
ISSN0036-0244
卷号95期号:SUPPL 2页码:S288-S295
摘要The present study reports the gamma-ray irradiation assisted polyacrylamide gel synthesis and optical, photoluminescence and supercapacitive performances of cobalt tungstates with special defect structure. The analysis of X-ray powder diffraction data showed that the purity and crystallinity of CoWO4 increased with the increasing of sintering temperature. X-ray photoelectron spectroscopy and energy spectrum analysis show that the high purity CoWO4 powders does not contain any other impurities. Color and optical properties analysis indicates that the high purity CoWO4 powders exhibits a strongest blue color than that of other samples. The photoluminescence spectrum shows three obvious emission bands in ultraviolet (340-375 nm), blue (424-490 nm), and green light emission (510 nm) regions under 220 nm xenon lamp excitation, which are ascribed to the organic impurities, the transition of T-3(1u) levels to the (1)A(1g) level, and the partially allowed transition of T-1g to (1)A(1g), respectively. Studies on electrochemical properties demonstrate that the CoWO4 powder has an excellent prospect in the supercapacitors for advanced electrochemical energy storage applications.
关键词CoWO4 sintering temperature optical properties emission band blue light emission supercapacitor
DOI10.1134/S0036024421150103
收录类别SCIE
语种英语
WOS研究方向Chemistry
WOS类目Chemistry, Physical
WOS记录号WOS:000742667400012
出版者MAIK NAUKA/INTERPERIODICA/SPRINGER
来源库WOS
引用统计
被引频次:2[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符https://ir.lut.edu.cn/handle/2XXMBERH/154962
专题理学院
通讯作者Wang, Shifa
作者单位1.Chongqing Three Gorges Univ, Sch Elect & Informat Engn, Chongqing 404000, Wanzhou, Peoples R China;
2.Lanzhou Univ Technol, Sch Sci, Lanzhou 730050, Peoples R China;
3.Chongqing Three Gorges Univ, Chongqing Key Lab Geol Environm Monitoring & Disa, Chongqing 404000, Wanzhou, Peoples R China;
4.China Acad Engn Phys, Inst Nucl Phys & Chem, Mianyang 621900, Sichuan, Peoples R China
第一作者单位理学院
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Gao, Huajing,Tang, Shengnan,Chen, Xiangyu,et al. Facile Synthesis of Cobalt Tungstate with Special Defect Structure with Enhanced Optical, Photoluminescence, and Supercapacitive Performances[J]. RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A,2021,95(SUPPL 2):S288-S295.
APA Gao, Huajing.,Tang, Shengnan.,Chen, Xiangyu.,Yu, Chuan.,Wang, Shifa.,...&Yang, Hua.(2021).Facile Synthesis of Cobalt Tungstate with Special Defect Structure with Enhanced Optical, Photoluminescence, and Supercapacitive Performances.RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A,95(SUPPL 2),S288-S295.
MLA Gao, Huajing,et al."Facile Synthesis of Cobalt Tungstate with Special Defect Structure with Enhanced Optical, Photoluminescence, and Supercapacitive Performances".RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A 95.SUPPL 2(2021):S288-S295.
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