Reconfigurable and NIR-responsive shape memory polymer containing bipheunit units and graphene
Yang, Jing1,2; Gong, Junhui1,3; Tao, Liming1,3; Tang, Zhangzhang1,2; Yang, Zenghui1; Cao, Pengrui1,3; Wang, Qihua1,3; Wang, Tingmei1,3; Luo, Heming2; Zhang, Yaoming1,3
2022-05
发表期刊POLYMER JOURNAL
ISSN0032-3896
卷号54期号:5页码:697-705
摘要A series of near-infrared (NIR)-responsive shape memory polymers based on biphenyl epoxy (BPEP/GR) were prepared by mixed amine thermal curing and photocuring with an iodized salt photoinitiator and aromatic ferrocene photosensitizer (IOD/FC) initiator. Differential scanning calorimetry (DSC), dynamic mechanical analysis (DMA), and tensile test results indicated that the addition of graphene to a biphenyl-containing epoxy resin matrix led to improvements in the transition temperature, strength, and shape memory properties. Shape recovery could be completed within a few seconds by NIR irradiation due to the high photothermal conversion efficiency of graphene. NIR laser irradiation promoted the activation and recombination of biphenyl units due to local heating. Thus, a reconfigured shape was obtained. This new reconfiguration method is expected to help realize the important application of BPEP/GR composites in the field of intelligent soft robots.
关键词Differential scanning calorimetry Epoxy resins Infrared devices Iron compounds Irradiation Organometallics Photosensitizers Shape optimization Tensile testing Epoxy Ferrocenes Near Infrared Near-infrared Photocuring Photoinitiators Polymer based Reconfigurable Shape memory polymers Thermal curing
DOI10.1038/s41428-021-00609-5
收录类别SCIE ; EI
语种英语
WOS研究方向Polymer Science
WOS类目Polymer Science
WOS记录号WOS:000745465100002
出版者SPRINGERNATURE
EI入藏号20220511544121
EI主题词Graphene
EI分类号741.1 Light/Optics ; 761 Nanotechnology ; 804 Chemical Products Generally ; 804.1 Organic Compounds ; 815.1.1 Organic Polymers ; 921.5 Optimization Techniques ; 944.6 Temperature Measurements
来源库WOS
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被引频次:2[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符https://ir.lut.edu.cn/handle/2XXMBERH/154834
专题附属中学
石油化工学院
通讯作者Luo, Heming; Zhang, Yaoming
作者单位1.Chinese Acad Sci, Lanzhou Inst Chem Phys, Key Lab Sci & Technol Wear & Protect Mat, Lanzhou 730000, Peoples R China;
2.Lanzhou Univ Technol, Coll Petrochem Technol, Lanzhou 730050, Peoples R China;
3.Univ Chinese Acad Sci, Ctr Mat Sci & Optoelect Engn, Beijing 100049, Peoples R China
第一作者单位石油化工学院
通讯作者单位石油化工学院
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GB/T 7714
Yang, Jing,Gong, Junhui,Tao, Liming,et al. Reconfigurable and NIR-responsive shape memory polymer containing bipheunit units and graphene[J]. POLYMER JOURNAL,2022,54(5):697-705.
APA Yang, Jing.,Gong, Junhui.,Tao, Liming.,Tang, Zhangzhang.,Yang, Zenghui.,...&Zhang, Yaoming.(2022).Reconfigurable and NIR-responsive shape memory polymer containing bipheunit units and graphene.POLYMER JOURNAL,54(5),697-705.
MLA Yang, Jing,et al."Reconfigurable and NIR-responsive shape memory polymer containing bipheunit units and graphene".POLYMER JOURNAL 54.5(2022):697-705.
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