Metal–Organic-Framework-Derived Nanostructures as Multifaceted Electrodes in Metal–Sulfur Batteries

doi:10.1002/adma.202008784

	Metal–Organic-Framework-Derived Nanostructures as Multifaceted Electrodes in Metal–Sulfur Batteries
	Yan, Rui 1; Ma, Tian 1; Cheng, Menghao 1; Tao, Xuefeng 1; Yang, Zhao 2; Ran, Fen2 ; Li, Shuang 3; Yin, Bo 1; Cheng, Chong 1,4; Yang, Wei 1
	2021-07
发表期刊	Advanced Materials
ISSN	09359648
卷号	33 期号:27
摘要	Metal-sulfur batteries (MSBs) are considered up-and-coming future-generation energy storage systems because of their prominent theoretical energy density. However, the practical applications of MSBs are still hampered by several critical challenges, i.e., the shuttle effects, sluggish redox kinetics, and low conductivity of sulfur species. Recently, benefiting from the high surface area, regulated networks, molecular/atomic-level reactive sites, the metal-organic frameworks (MOFs)-derived nanostructures have emerged as efficient and durable multifaceted electrodes in MSBs. Herein, a timely review is presented on recent advancements in designing MOF-derived electrodes, including fabricating strategies, composition management, topography control, and electrochemical performance assessment. Particularly, the inherent charge transfer, intrinsic polysulfide immobilization, and catalytic conversion on designing and engineering of MOF nanostructures for efficient MSBs are systematically discussed. In the end, the essence of how MOFs’ nanostructures influence their electrochemical properties in MSBs and conclude the future tendencies regarding the construction of MOF-derived electrodes in MSBs is exposed. It is believed that this progress review will provide significant experimental/theoretical guidance in designing and understanding the MOF-derived nanostructures as multifaceted electrodes, thus offering promising orientations for the future development of fast-kinetic and robust MSBs in broad energy fields. © 2021 The Authors. Advanced Materials published by Wiley-VCH GmbH
关键词	Charge transfer Electric batteries Energy storage Metal-Organic Frameworks Metals Nanostructures Organic polymers Organometallics Sulfur Topography Catalytic conversion Critical challenges Electrochemical performance Energy storage systems Future generations High surface area Metalorganic frameworks (MOFs) Topography controls
DOI	10.1002/adma.202008784
收录类别	EI ; SCIE
语种	英语
WOS研究方向	Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics
WOS类目	Chemistry, Multidisciplinary ; Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied ; Physics, Condensed Matter
WOS记录号	WOS:000653589400001
出版者	John Wiley and Sons Inc
EI入藏号	20212110414415
EI主题词	Electrochemical electrodes
EI分类号	525.7 Energy Storage ; 702.1 Electric Batteries ; 761 Nanotechnology ; 802.2 Chemical Reactions ; 804 Chemical Products Generally ; 804.1 Organic Compounds ; 815.1.1 Organic Polymers ; 933 Solid State Physics ; 951 Materials Science
来源库	WOS
引用统计	被引频次：55[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	https://ir.lut.edu.cn/handle/2XXMBERH/151132
专题	材料科学与工程学院
通讯作者	Li, Shuang; Cheng, Chong; Yang, Wei
作者单位	1.Sichuan Univ, West China Hosp, State Key Lab Polymer Mat Engn, Coll Polymer Sci & Engn,Dept Ultrasound, Chengdu 610065, Peoples R China; 2.Lanzhou Univ Technol, State Key Lab Adv Proc & Recycling Nonferrous Met, Lanzhou 730050, Gansu, Peoples R China; 3.Tech Univ Berlin, Dept Chem, Funct Mat, Hardenbergstr 40, D-10623 Berlin, Germany; 4.Free Univ Berlin, Dept Chem & Biochem, Takustr 3, D-14195 Berlin, Germany
推荐引用方式 GB/T 7714	Yan, Rui,Ma, Tian,Cheng, Menghao,et al. Metal–Organic-Framework-Derived Nanostructures as Multifaceted Electrodes in Metal–Sulfur Batteries[J]. Advanced Materials,2021,33(27).
APA	Yan, Rui.,Ma, Tian.,Cheng, Menghao.,Tao, Xuefeng.,Yang, Zhao.,...&Yang, Wei.(2021).Metal–Organic-Framework-Derived Nanostructures as Multifaceted Electrodes in Metal–Sulfur Batteries.Advanced Materials,33(27).
MLA	Yan, Rui,et al."Metal–Organic-Framework-Derived Nanostructures as Multifaceted Electrodes in Metal–Sulfur Batteries".Advanced Materials 33.27(2021).