Synthesis of a novel phosphate-containing highly transparent PMMA copolymer with enhanced thermal and flame retardant properties

doi:10.1002/pat.4784

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	Synthesis of a novel phosphate-containing highly transparent PMMA copolymer with enhanced thermal and flame retardant properties
	Yang, Baoping; Wang, Lurong; Guo, Yongliang; Zhang, Yabin; Wang, Niannian; Cui, Jinfeng; Guo, Junhong; Tian, Li
	2020-03-01
发表期刊	Polymers for Advanced Technologies
ISSN	10427147
卷号	31 期号:3 页码:472-481
摘要	A novel poly(methyl methacrylate) (PMMA)-based copolymer (PMMA-co-BDPA) rich in aromatic rings was synthesized via radical copolymerization between a phosphorus-containing acrylic monomer (BDPA) and methyl methacrylate (MMA). UV-vis spectroscopy demonstrated that the copolymer had high transparency. Thermogravimetric analysis (TGA) and a differential scanning calorimeter (DSC) were used to test the thermal properties of the composites. Additionally, the PMMA-co-BDPA-15 copolymer exhibited a 23% increase in the limited oxygen index (LOI) value. A cone calorimeter test indicated that the peak heat release rate (pk-HRR) of PMMA-co-BDPA was reduced by 29.2% compared with that of pure PMMA, and the carbon yield of burning was obviously increased. The combined test results demonstrated that the prepared copolymer material had good transparency, thermal stability, and flame retardancy. © 2019 John Wiley & Sons, Ltd.
关键词	Acrylic monomers Calorimeters Copolymerization Differential scanning calorimetry Esters Transparency Ultraviolet visible spectroscopy Differential scanning calorimeters Flame retardancy Flame retardant properties Limited oxygen index Methyl methacrylates Peak heat release rates Poly(methyl methacrylate) (PMMA) Radical copolymerization
DOI	10.1002/pat.4784
收录类别	EI ; SCIE
语种	英语
WOS研究方向	Polymer Science
WOS类目	Polymer Science
WOS记录号	WOS:000500369800001
出版者	John Wiley and Sons Ltd
EI入藏号	20195007824155
EI主题词	Thermogravimetric analysis
EI分类号	741.1 Light/Optics ; 801 Chemistry ; 804.1 Organic Compounds ; 815.2 Polymerization ; 944.5 Temperature Measuring Instruments ; 944.6 Temperature Measurements
引用统计	被引频次：17[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	https://ir.lut.edu.cn/handle/2XXMBERH/150809
专题	图书馆石油化工学院实验室建设与管理处
通讯作者	Tian, Li
作者单位	Lanzhou Univ Technol, Coll Petrochem Technol, Lanzhou 730050, Gansu, Peoples R China
第一作者单位	石油化工学院
通讯作者单位	石油化工学院
第一作者的第一单位	石油化工学院
推荐引用方式 GB/T 7714	Yang, Baoping,Wang, Lurong,Guo, Yongliang,et al. Synthesis of a novel phosphate-containing highly transparent PMMA copolymer with enhanced thermal and flame retardant properties[J]. Polymers for Advanced Technologies,2020,31(3):472-481.
APA	Yang, Baoping.,Wang, Lurong.,Guo, Yongliang.,Zhang, Yabin.,Wang, Niannian.,...&Tian, Li.(2020).Synthesis of a novel phosphate-containing highly transparent PMMA copolymer with enhanced thermal and flame retardant properties.Polymers for Advanced Technologies,31(3),472-481.
MLA	Yang, Baoping,et al."Synthesis of a novel phosphate-containing highly transparent PMMA copolymer with enhanced thermal and flame retardant properties".Polymers for Advanced Technologies 31.3(2020):472-481.