Mesoporous carbons for supercapacitors obtained by the pyrolysis of block copolymers
Wang Yong1; Kong Ling-bin1,2; Li Xiao-ming1; Ran Fen1; Luo Yong-chun2; Kang Long2
2015-08-01
发表期刊Xinxing Tan Cailiao/New Carbon Materials
ISSN10078827
卷号30期号:4页码:302-309
摘要Novel mesoporous carbons were prepared by the simple pyrolysis of block-copolymers, polyacrylonitrile-b-polystyrene-b-polyacrylonitrile (PAN-b-PS-b-PAN), in which PAN generates a carbon network and PS is released to form mesopores after pyrolysis. The block-copolymers were synthesized by reversible addition-fragmentation chain transfer (RAFT) polymerization and the molecular weight of each polymer block can be designed to tailor the porous structure of the mesoporous carbons. The carbons have high specific surface areas and a well-controlled mesopore size. The best mesoporous carbon has a high specific capacitance of 185 F·g-1 at 0.625 A·g-1 with a high power capability and a remarkable cycle stability in 2 mol/L KOH aqueous electrolyte. ©, 2015, Xinxing Tan Cailiao/New Carbon Materials. All right reserved.
关键词Carbon Carbonization Electrolytes Energy storage Mesoporous materials Potassium hydroxide Pyrolysis Supercapacitor Aqueous electrolyte Cycle stability High power capability High specific capacitances High specific surface area Mesoporous carbon Porous structures Reversible addition-fragmentation chain transfer polymerization
DOI10.1016/s1872-5805(15)60191-3
收录类别EI
语种英语
WOS研究方向Materials Science
WOS类目Materials Science, Multidisciplinary
WOS记录号WOS:000361585300003
出版者Institute of Metal Research Chinese Academy of Sciences
EI入藏号20154401462135
EI主题词Block copolymers
EI分类号525.7 Energy Storage ; 802.2 Chemical Reactions ; 804 Chemical Products Generally ; 804.2 Inorganic Compounds ; 815.1 Polymeric Materials
引用统计
被引频次:13[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符https://ir.lut.edu.cn/handle/2XXMBERH/150338
专题设计艺术学院
材料科学与工程学院
通讯作者Kong Ling-bin
作者单位1.Lanzhou Univ Technol, Sch Mat Sci & Engn, State Key Lab Adv Proc & Recycling Nonferrous Met, Lanzhou 730050, Peoples R China;
2.Lanzhou Univ Technol, Sch Mat Sci & Engn, Lanzhou 730050, Peoples R China
第一作者单位材料科学与工程学院
通讯作者单位材料科学与工程学院
第一作者的第一单位材料科学与工程学院
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Wang Yong,Kong Ling-bin,Li Xiao-ming,et al. Mesoporous carbons for supercapacitors obtained by the pyrolysis of block copolymers[J]. Xinxing Tan Cailiao/New Carbon Materials,2015,30(4):302-309.
APA Wang Yong,Kong Ling-bin,Li Xiao-ming,Ran Fen,Luo Yong-chun,&Kang Long.(2015).Mesoporous carbons for supercapacitors obtained by the pyrolysis of block copolymers.Xinxing Tan Cailiao/New Carbon Materials,30(4),302-309.
MLA Wang Yong,et al."Mesoporous carbons for supercapacitors obtained by the pyrolysis of block copolymers".Xinxing Tan Cailiao/New Carbon Materials 30.4(2015):302-309.
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