Mesoporous carbons for supercapacitors obtained by the pyrolysis of block copolymers | |
Wang Yong1; Kong Ling-bin1,2; Li Xiao-ming1; Ran Fen1; Luo Yong-chun2; Kang Long2 | |
2015-08-01 | |
发表期刊 | Xinxing Tan Cailiao/New Carbon Materials |
ISSN | 10078827 |
卷号 | 30期号:4页码:302-309 |
摘要 | Novel mesoporous carbons were prepared by the simple pyrolysis of block-copolymers, polyacrylonitrile-b-polystyrene-b-polyacrylonitrile (PAN-b-PS-b-PAN), in which PAN generates a carbon network and PS is released to form mesopores after pyrolysis. The block-copolymers were synthesized by reversible addition-fragmentation chain transfer (RAFT) polymerization and the molecular weight of each polymer block can be designed to tailor the porous structure of the mesoporous carbons. The carbons have high specific surface areas and a well-controlled mesopore size. The best mesoporous carbon has a high specific capacitance of 185 F·g-1 at 0.625 A·g-1 with a high power capability and a remarkable cycle stability in 2 mol/L KOH aqueous electrolyte. ©, 2015, Xinxing Tan Cailiao/New Carbon Materials. All right reserved. |
关键词 | Carbon Carbonization Electrolytes Energy storage Mesoporous materials Potassium hydroxide Pyrolysis Supercapacitor Aqueous electrolyte Cycle stability High power capability High specific capacitances High specific surface area Mesoporous carbon Porous structures Reversible addition-fragmentation chain transfer polymerization |
DOI | 10.1016/s1872-5805(15)60191-3 |
收录类别 | EI |
语种 | 英语 |
WOS研究方向 | Materials Science |
WOS类目 | Materials Science, Multidisciplinary |
WOS记录号 | WOS:000361585300003 |
出版者 | Institute of Metal Research Chinese Academy of Sciences |
EI入藏号 | 20154401462135 |
EI主题词 | Block copolymers |
EI分类号 | 525.7 Energy Storage ; 802.2 Chemical Reactions ; 804 Chemical Products Generally ; 804.2 Inorganic Compounds ; 815.1 Polymeric Materials |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | https://ir.lut.edu.cn/handle/2XXMBERH/150338 |
专题 | 设计艺术学院 材料科学与工程学院 |
通讯作者 | Kong Ling-bin |
作者单位 | 1.Lanzhou Univ Technol, Sch Mat Sci & Engn, State Key Lab Adv Proc & Recycling Nonferrous Met, Lanzhou 730050, Peoples R China; 2.Lanzhou Univ Technol, Sch Mat Sci & Engn, Lanzhou 730050, Peoples R China |
第一作者单位 | 材料科学与工程学院 |
通讯作者单位 | 材料科学与工程学院 |
第一作者的第一单位 | 材料科学与工程学院 |
推荐引用方式 GB/T 7714 | Wang Yong,Kong Ling-bin,Li Xiao-ming,et al. Mesoporous carbons for supercapacitors obtained by the pyrolysis of block copolymers[J]. Xinxing Tan Cailiao/New Carbon Materials,2015,30(4):302-309. |
APA | Wang Yong,Kong Ling-bin,Li Xiao-ming,Ran Fen,Luo Yong-chun,&Kang Long.(2015).Mesoporous carbons for supercapacitors obtained by the pyrolysis of block copolymers.Xinxing Tan Cailiao/New Carbon Materials,30(4),302-309. |
MLA | Wang Yong,et al."Mesoporous carbons for supercapacitors obtained by the pyrolysis of block copolymers".Xinxing Tan Cailiao/New Carbon Materials 30.4(2015):302-309. |
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