Effects of functional groups of -NH2 and -NO2 on water adsorption ability of Zr-based MOFs (UiO-66)
Tang, Xingchang1,2; Luo, Yongwei1,2,3; Zhang, Zhijian2; Ding, Wanwu2; Liu, Dexue2; Wang, Jingchuan3; Guo, Li3; Wen, Ming3
2021-03-01
发表期刊CHEMICAL PHYSICS
ISSN0301-0104
卷号543
摘要The high surface areas and tunable properties of Zr-based MOFs make them as attractive materials for gas capture, storage, and separation. In this work, UiO-66, one kinds of Zr-based MOFs, functionalized by single or binary -NO2 and -NH2 groups are synthesized. Water adsorption ability and hydrophilicity of UiO-66 and functionalized UiO-66-X were investigated. It is found that surface area of UiO-66 is decreased after introducing functional groups, while hydrophilicity of UiO-66 increased after functionalized with -NO2 and -NH2. Therefore, after balance the effects of surface area and hydrophilicity, UiO-66-NH2 shows the best water adsorption propriety.
关键词UiO-66-X Water adsorption Surface area Hydrophilicity
DOI10.1016/j.chemphys.2021.111093
收录类别SCOPUS ; SCIE
语种英语
WOS研究方向Chemistry ; Physics
WOS类目Chemistry, Physical ; Physics, Atomic, Molecular & Chemical
WOS记录号WOS:000674256400010
出版者ELSEVIER
来源库WOS
引用统计
被引频次:16[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符https://ir.lut.edu.cn/handle/2XXMBERH/148910
专题材料科学与工程学院
省部共建有色金属先进加工与再利用国家重点实验室
通讯作者Tang, Xingchang; Wang, Jingchuan
作者单位1.State Key Lab Adv Proc & Recycling Nonferrous Met, Lanzhou 730050, Gansu, Peoples R China;
2.Lanzhou Univ Technol, Sch Mat Sci & Engn, Lanzhou 730050, Gansu, Peoples R China;
3.China Acad Engn Phys, Inst Mat, Jiangyou, Peoples R China
第一作者单位材料科学与工程学院
通讯作者单位材料科学与工程学院
推荐引用方式
GB/T 7714
Tang, Xingchang,Luo, Yongwei,Zhang, Zhijian,et al. Effects of functional groups of -NH2 and -NO2 on water adsorption ability of Zr-based MOFs (UiO-66)[J]. CHEMICAL PHYSICS,2021,543.
APA Tang, Xingchang.,Luo, Yongwei.,Zhang, Zhijian.,Ding, Wanwu.,Liu, Dexue.,...&Wen, Ming.(2021).Effects of functional groups of -NH2 and -NO2 on water adsorption ability of Zr-based MOFs (UiO-66).CHEMICAL PHYSICS,543.
MLA Tang, Xingchang,et al."Effects of functional groups of -NH2 and -NO2 on water adsorption ability of Zr-based MOFs (UiO-66)".CHEMICAL PHYSICS 543(2021).
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