Methanol to Aromatic Reaction over HZSM-5: Co-Effect Desilication and SiO2 Deposition

doi:10.1134/S0023158421030058

IR > 石油化工学院

	Methanol to Aromatic Reaction over HZSM-5: Co-Effect Desilication and SiO2 Deposition
	Li, Hui; Dong, Peng; Ji, Dong; Zhao, Xinhong; Li, Chunqiang; Li, Guixian
	2021-05
发表期刊	KINETICS AND CATALYSIS
ISSN	0023-1584
卷号	62 期号:3 页码:418-427
摘要	Inthis work Si/HZSM-5-0.09M catalyst was prepared using desilication and regrowth of SiO2 method, which was characterized by XRF, XRD, SEM, NH3-TPD, and N-2 adsorption/desorption. Meanwhile, the structure-activity relationship was comprehensively discussed. The results revealed that the aromatics total selectivity of Si/HZSM-5-0.09M catalyst was significantly improved, from 33 to 54.8% compared to HZSM-5 under the optimal conditions. Also, the selectivity of p-xylene over Si/HZSM-5-0.09M catalyst increased from 4.6 to 19.8% compared to HZSM-5. The total selectivity of benzene, toluene, and xylene over Si/HZSM-5-0.09M catalyst was significantly improved by 66.1% compared to that of HZSM-5. Thus, an excellent catalytic effect has been found, which indicates that the SiO2 deposition on the surface favors the enhancement of the p-xylene selectivity in the methanol aromatization reaction. [GRAPHICS] .
关键词	HZSM-5 methanol p-xylene selectivity MTA reaction
DOI	10.1134/S0023158421030058
收录类别	SCOPUS ; SCIE
语种	英语
WOS研究方向	Chemistry
WOS类目	Chemistry, Physical
WOS记录号	WOS:000660025600010
出版者	PLEIADES PUBLISHING INC
来源库	WOS
引用统计	被引频次：1[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	https://ir.lut.edu.cn/handle/2XXMBERH/148679
专题	石油化工学院
通讯作者	Li, Guixian
作者单位	Lanzhou Univ Technol, Coll Petrochem Technol, Lanzhou 730050, Peoples R China
第一作者单位	石油化工学院
通讯作者单位	石油化工学院
第一作者的第一单位	石油化工学院
推荐引用方式 GB/T 7714	Li, Hui,Dong, Peng,Ji, Dong,et al. Methanol to Aromatic Reaction over HZSM-5: Co-Effect Desilication and SiO2 Deposition[J]. KINETICS AND CATALYSIS,2021,62(3):418-427.
APA	Li, Hui,Dong, Peng,Ji, Dong,Zhao, Xinhong,Li, Chunqiang,&Li, Guixian.(2021).Methanol to Aromatic Reaction over HZSM-5: Co-Effect Desilication and SiO2 Deposition.KINETICS AND CATALYSIS,62(3),418-427.
MLA	Li, Hui,et al."Methanol to Aromatic Reaction over HZSM-5: Co-Effect Desilication and SiO2 Deposition".KINETICS AND CATALYSIS 62.3(2021):418-427.

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