Third-order nonlinear optical properties of axially modified indium phthalocyanines with alkyl chains

doi:10.1039/d1nj00775k

IR > 石油化工学院

	Third-order nonlinear optical properties of axially modified indium phthalocyanines with alkyl chains
	Chen, Lan 1; He, Chunying 1; Liu, Dongmei 1; Zheng, Yi2 ; Li, Wanlu 1; Zu, Yanli 1
	2021-06-14
发表期刊	NEW JOURNAL OF CHEMISTRY
ISSN	1144-0546
卷号	45 期号:22 页码:10021-10030
摘要	Increasing the electron density on the phthalocyanine (Pc) ring is an effective approach for ensuring an excellent third-order nonlinear optical (NLO) property. Herein, a series of axially substituted indium Pcs (axial substituent: ethyl, n-propyl, n-butyl, n-pentyl) were synthesized on the basis of tetra-[3-(2-ethoxy)ethoxy] indium phthalocyanine chloride (InClPc). The third-order nonlinear optical properties were investigated by the Z-scan technique at 532 nm with 4 ns laser pulses. All the axially alkyl substituted InPcs showed a better nonlinear absorption response than InClPc. The NLO properties of the axially substituted Pcs got better with the increased length of the alkyl chain. The effect of alkyl chain substituents on the nonlinear absorption of indium phthalocyanine was demonstrated through their optical physical parameters (Phi(F), k(ST), Phi(T), and tau(T)).
关键词	Chlorine compounds Indium compounds Microcomputers Optical properties Alkyl chain Effective approaches NLO properties Nonlinear absorptions Physical parameters Third order nonlinear optical properties Third-order nonlinear optical Z-scan technique
DOI	10.1039/d1nj00775k
收录类别	SCIE ; IC ; SCOPUS ; EI
语种	英语
WOS研究方向	Chemistry
WOS类目	Chemistry, Multidisciplinary
WOS记录号	WOS:000651843300001
出版者	ROYAL SOC CHEMISTRY
EI入藏号	20212410496613
EI主题词	Nonlinear optics
EI分类号	722.4 Digital Computers and Systems - 741.1 Light/Optics - 741.1.1 Nonlinear Optics
来源库	WOS
引用统计	被引频次：5[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	https://ir.lut.edu.cn/handle/2XXMBERH/148239
专题	石油化工学院
通讯作者	He, Chunying; Zheng, Yi
作者单位	1.Heilongjiang Univ, Sch Chem & Mat Sci, Key Lab Funct Inorgan Mat Chem, Minist Educ, Harbin 150080, Peoples R China; 2.Lanzhou Univ Technol, Sch Petrochem Engn, Lanzhou 730050, Peoples R China
通讯作者单位	兰州理工大学
推荐引用方式 GB/T 7714	Chen, Lan,He, Chunying,Liu, Dongmei,et al. Third-order nonlinear optical properties of axially modified indium phthalocyanines with alkyl chains[J]. NEW JOURNAL OF CHEMISTRY,2021,45(22):10021-10030.
APA	Chen, Lan,He, Chunying,Liu, Dongmei,Zheng, Yi,Li, Wanlu,&Zu, Yanli.(2021).Third-order nonlinear optical properties of axially modified indium phthalocyanines with alkyl chains.NEW JOURNAL OF CHEMISTRY,45(22),10021-10030.
MLA	Chen, Lan,et al."Third-order nonlinear optical properties of axially modified indium phthalocyanines with alkyl chains".NEW JOURNAL OF CHEMISTRY 45.22(2021):10021-10030.