Metal-Organic-Framework-Derived Nanostructures as Multifaceted Electrodes in Metal-Sulfur Batteries

doi:10.1002/adma.202008784

	Metal-Organic-Framework-Derived Nanostructures as Multifaceted Electrodes in Metal-Sulfur Batteries
	Yan, Rui 1; Ma, Tian 1; Cheng, Menghao 1; Tao, Xuefeng 1; Yang, Zhao 2; Ran, Fen2 ; Li, Shuang 3; Yin, Bo 1; Cheng, Chong 1,4; Yang, Wei 1
	2021
发表期刊	ADVANCED MATERIALS
ISSN	0935-9648
卷号	33 期号:27
摘要	Metal-sulfur batteries (MSBs) are considered up-and-coming future-generation energy storage systems because of their prominent theoretical energy density. However, the practical applications of MSBs are still hampered by several critical challenges, i.e., the shuttle effects, sluggish redox kinetics, and low conductivity of sulfur species. Recently, benefiting from the high surface area, regulated networks, molecular/atomic-level reactive sites, the metal-organic frameworks (MOFs)-derived nanostructures have emerged as efficient and durable multifaceted electrodes in MSBs. Herein, a timely review is presented on recent advancements in designing MOF-derived electrodes, including fabricating strategies, composition management, topography control, and electrochemical performance assessment. Particularly, the inherent charge transfer, intrinsic polysulfide immobilization, and catalytic conversion on designing and engineering of MOF nanostructures for efficient MSBs are systematically discussed. In the end, the essence of how MOFs' nanostructures influence their electrochemical properties in MSBs and conclude the future tendencies regarding the construction of MOF-derived electrodes in MSBs is exposed. It is believed that this progress review will provide significant experimental/theoretical guidance in designing and understanding the MOF-derived nanostructures as multifaceted electrodes, thus offering promising orientations for the future development of fast-kinetic and robust MSBs in broad energy fields.
关键词	energy storage materials metal‐ organic frameworks metal– sulfur batteries nanostructures porous carbon polysulfide catalysts polysulfide electrodes
DOI	10.1002/adma.202008784
收录类别	SCIE ; SCOPUS ; EI
语种	英语
WOS研究方向	Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics
WOS类目	Chemistry, Multidisciplinary ; Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied ; Physics, Condensed Matter
WOS记录号	WOS:000653589400001
出版者	WILEY-V C H VERLAG GMBH
引用统计	被引频次：55[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	https://ir.lut.edu.cn/handle/2XXMBERH/148202
专题	材料科学与工程学院
作者单位	1.Sichuan Univ, West China Hosp, State Key Lab Polymer Mat Engn, Coll Polymer Sci & Engn,Dept Ultrasound, Chengdu 610065, Peoples R China; 2.Lanzhou Univ Technol, State Key Lab Adv Proc & Recycling Nonferrous Met, Lanzhou 730050, Gansu, Peoples R China; 3.Tech Univ Berlin, Dept Chem, Funct Mat, Hardenbergstr 40, D-10623 Berlin, Germany; 4.Free Univ Berlin, Dept Chem & Biochem, Takustr 3, D-14195 Berlin, Germany
推荐引用方式 GB/T 7714	Yan, Rui,Ma, Tian,Cheng, Menghao,et al. Metal-Organic-Framework-Derived Nanostructures as Multifaceted Electrodes in Metal-Sulfur Batteries[J]. ADVANCED MATERIALS,2021,33(27).
APA	Yan, Rui.,Ma, Tian.,Cheng, Menghao.,Tao, Xuefeng.,Yang, Zhao.,...&Yang, Wei.(2021).Metal-Organic-Framework-Derived Nanostructures as Multifaceted Electrodes in Metal-Sulfur Batteries.ADVANCED MATERIALS,33(27).
MLA	Yan, Rui,et al."Metal-Organic-Framework-Derived Nanostructures as Multifaceted Electrodes in Metal-Sulfur Batteries".ADVANCED MATERIALS 33.27(2021).