Glass-like Cuprous Iodide Complexes with Photoluminescence Tuning and Two-photon Emission Properties

doi:10.7503/cjcu20190657

	Glass-like Cuprous Iodide Complexes with Photoluminescence Tuning and Two-photon Emission Properties
	Yin, Shaoyun 1,2; Zhang, Luyin1,3 ; Wang, Zheng 1; Pan, Mei 1
	2020-04-10
发表期刊	Gaodeng Xuexiao Huaxue Xuebao/Chemical Journal of Chinese Universities
ISSN	02510790
卷号	41 期号:4 页码:646-651
摘要	Eight kinds of glass-like cuprous iodide complexes with Cu2I2L2 configurations were self-assembled from CuI with semi-flexible 3-pebtd ligand with unsaturated π-backbone and bipodal pyridine terminals in different solvents. The complexes were characterized by X-ray single crystal diffraction, X-ray powder diffraction, elemental analysis, and so on. The photophysical properties of the complexes were studied, and the results show that the one-photon emissions of the complexes obtained in different solvents show single fluorescence bands assigning to the halogen to ligand charge transfer(3XLCT). The luminescent colors of the complexes were adjustable from 492 to 518 nm, and the quantum yield was 33.1%~68.5%. At the same time, these complexes exhibit excellent two-photon emission properties and are expected to be used in the field of biological imaging. © 2020, Higher Education Press. All right reserved.
关键词	Charge transfer Copper compounds Diffraction Glass Ligands Photons Single crystals X ray powder diffraction X rays Biological imaging Different solvents Fluorescence band Luminescent colors Photon emissions Photophysical properties Two-photon emission X-ray single-crystal diffraction
DOI	10.7503/cjcu20190657
收录类别	EI
语种	中文
出版者	Higher Education Press Limited Company
EI入藏号	20201808589947
EI主题词	Iodine compounds
来源库	Compendex
分类代码	801.4 Physical Chemistry - 802.2 Chemical Reactions - 812.3 Glass - 931.3 Atomic and Molecular Physics - 932.1 High Energy Physics - 933.1 Crystalline Solids
引用统计	被引频次[WOS]：0 [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	https://ir.lut.edu.cn/handle/2XXMBERH/115677
专题	省部共建有色金属先进加工与再利用国家重点实验室
作者单位	1.School of Chemistry, Sun Yat-Sen University, Guangzhou; 510275, China; 2.Analysis and Test Center, Guangdong University of Technology, Guangzhou; 510006, China; 3.State Key Laboratory of Advanced Processing and Recycling of Nonferrous Metals, School of Materials Science and Engineering, Lanzhou University of Technology, Lanzhou; 730050, China
推荐引用方式 GB/T 7714	Yin, Shaoyun,Zhang, Luyin,Wang, Zheng,et al. Glass-like Cuprous Iodide Complexes with Photoluminescence Tuning and Two-photon Emission Properties[J]. Gaodeng Xuexiao Huaxue Xuebao/Chemical Journal of Chinese Universities,2020,41(4):646-651.
APA	Yin, Shaoyun,Zhang, Luyin,Wang, Zheng,&Pan, Mei.(2020).Glass-like Cuprous Iodide Complexes with Photoluminescence Tuning and Two-photon Emission Properties.Gaodeng Xuexiao Huaxue Xuebao/Chemical Journal of Chinese Universities,41(4),646-651.
MLA	Yin, Shaoyun,et al."Glass-like Cuprous Iodide Complexes with Photoluminescence Tuning and Two-photon Emission Properties".Gaodeng Xuexiao Huaxue Xuebao/Chemical Journal of Chinese Universities 41.4(2020):646-651.