Carbon modified porous γ-Fe2O3 as anode for high performance Li-ion batteries
Duan, Chaoyu1; Meng, Yanshuang1,3; Du, Mengqi1; Wang, Lei1; Zhang, Yue2
2018-07-01
发表期刊Journal of Materials Science: Materials in Electronics
ISSN09574522
卷号29期号:14页码:11936-11944
摘要Carbon modified porous γ-Fe2O3 particles (PFe2O3–C) are synthesized by a high temperature calcination method using sodium chloride as a template. During the nucleation and carbonation process, the Fe(NO3)3–C10H15N5 complex uniformly dispersed on the surface of NaCl particles which can limit its longitudinal growth, thus forming independent and homogeneous nanoparticles with a diameter of about 30 nm. Because of this special structure, the γ-Fe2O3 particles have a sufficient interspace between them, which can not only provide a large number of active sites for storing lithium ions, but also shorten diffusion length for lithium ion transport. The introduction of carbon can offer additional lithium ion storage and improve overall electrical conductivity. This PFe2O3–C electrode exhibits excellent rate performance (1139, 1067, and 972 mAh g−1 at 2, 5, and 10 C, respectively, 1 C = 924 mAh g−1) and cycle performance (up to 2100 mAh g−1 after 200 cycles at 0.3 C). © 2018, Springer Science+Business Media, LLC, part of Springer Nature.
关键词Carbon Electrodes Hematite Ions Sodium chloride Carbonation process Electrical conductivity High-temperature calcination Homogeneous nanoparticles Lithium ion storages Lithium-ion transport Longitudinal growth Number of active sites
DOI10.1007/s10854-018-9295-6
收录类别EI ; SCIE
语种英语
WOS研究方向Engineering ; Materials Science ; Physics
WOS类目Engineering, Electrical & Electronic ; Materials Science, Multidisciplinary ; Physics, Applied ; Physics, Condensed Matter
WOS记录号WOS:000435671800036
出版者Springer New York LLC
EI入藏号20182105224036
EI主题词Lithium-ion batteries
EI分类号482.2 Minerals - 804 Chemical Products Generally
来源库Compendex
分类代码482.2 Minerals - 804 Chemical Products Generally
引用统计
被引频次:3[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符https://ir.lut.edu.cn/handle/2XXMBERH/114591
专题材料科学与工程学院
通讯作者Meng, Yanshuang; Zhang, Yue
作者单位1.Lanzhou Univ Technol, Sch Mat Sci & Engn, Lanzhou 730050, Gansu, Peoples R China;
2.Texas A&M Univ Kingsville, Dept Mech & Ind Engn, Kingsville, TX 78363 USA;
3.State Key Lab Adv Proc & Recycling Nonferrous Met, Lanzhou 730050, Gansu, Peoples R China
第一作者单位材料科学与工程学院
通讯作者单位材料科学与工程学院
第一作者的第一单位材料科学与工程学院
推荐引用方式
GB/T 7714
Duan, Chaoyu,Meng, Yanshuang,Du, Mengqi,et al. Carbon modified porous γ-Fe2O3 as anode for high performance Li-ion batteries[J]. Journal of Materials Science: Materials in Electronics,2018,29(14):11936-11944.
APA Duan, Chaoyu,Meng, Yanshuang,Du, Mengqi,Wang, Lei,&Zhang, Yue.(2018).Carbon modified porous γ-Fe2O3 as anode for high performance Li-ion batteries.Journal of Materials Science: Materials in Electronics,29(14),11936-11944.
MLA Duan, Chaoyu,et al."Carbon modified porous γ-Fe2O3 as anode for high performance Li-ion batteries".Journal of Materials Science: Materials in Electronics 29.14(2018):11936-11944.
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