Synthesis and flame retardant properties of phosphorus hybrid monomer VOPP grafted polystyrene copolymer | |
Cui, Jinfeng; Xu, Fen; Guo, Junhong; Bao, Xuemei; Guo, Yongliang; Mu, Bo; Tian, Li; Yang, Baoping | |
2017-10-01 | |
发表期刊 | Fuhe Cailiao Xuebao/Acta Materiae Compositae Sinica |
ISSN | 10003851 |
卷号 | 34期号:10页码:2141-2149 |
摘要 | The vinyl-terminated oligophosphate hybrid monomer (VOPP) was synthesized by step-reaction polymerization using phenyl dichlorophosphate(PDCP), ethylene glycol(EG), methanol, hydroxyethyl methylacrylate(HEMA), VOPP and styrene (St) by graft copolymerization preparation of phosphorus element of hybrid monomer grafted polystyrene copolymer (VOPP-co-St). The structural characteristics and average molecular weight of VOPP were explored by FTIR and gel permeation chromatography(GPC).The thermal stability and flame-retardant properties of the VOPP-co-St were evaluated by TGA, limit oxygen index(LOI) and microscale combustion calorimeter; The morphology and composition of the char layer were investigated by SEM and XPS. The thermal decomposition activation energy(Ea) of VOPP-co-St was calculated by Flynn-Wall-Ozawa(FWO) method. The results show that the temperature of maximum decomposition rate, residual mass and LOI of VOPP-co-St increase with the increase of VOPP content, peak heat release rate(PHRR) and total heat release(THR) reduce with the increase of VOPP content, and droplet phenomenon disappeare, while Ea increases with the increase of degradation conversion rate. © 2017, Chinese Society for Composite Materials. All right reserved. |
关键词 | Activation energy Copolymerization Decomposition Ethylene Ethylene glycol Gel permeation chromatography Molecular oxygen Phosphorus Polystyrenes Styrene Element hybrid Flame retardant properties Gel permeation chromatography (GPC) Graft co polymerizations Macromers Microscale combustion calorimeters Morphology and composition Thermal decomposition activation energies |
DOI | 10.13801/j.cnki.fhclxb.20170117.004 |
收录类别 | EI |
语种 | 中文 |
出版者 | Beijing University of Aeronautics and Astronautics (BUAA) |
EI入藏号 | 20174804465118 |
EI主题词 | Grafting (chemical) |
EI分类号 | 802.2 Chemical Reactions - 802.3 Chemical Operations - 804 Chemical Products Generally - 815.1.1 Organic Polymers - 815.2 Polymerization |
来源库 | Compendex |
分类代码 | 802.2 Chemical Reactions - 802.3 Chemical Operations - 804 Chemical Products Generally - 815.1.1 Organic Polymers - 815.2 Polymerization |
引用统计 | 无
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文献类型 | 期刊论文 |
条目标识符 | https://ir.lut.edu.cn/handle/2XXMBERH/114005 |
专题 | 石油化工学院 图书馆 实验室建设与管理处 |
作者单位 | Petrochemistry College, Lanzhou University of Technology, Lanzhou; 730050, China |
第一作者单位 | 兰州理工大学 |
第一作者的第一单位 | 兰州理工大学 |
推荐引用方式 GB/T 7714 | Cui, Jinfeng,Xu, Fen,Guo, Junhong,et al. Synthesis and flame retardant properties of phosphorus hybrid monomer VOPP grafted polystyrene copolymer[J]. Fuhe Cailiao Xuebao/Acta Materiae Compositae Sinica,2017,34(10):2141-2149. |
APA | Cui, Jinfeng.,Xu, Fen.,Guo, Junhong.,Bao, Xuemei.,Guo, Yongliang.,...&Yang, Baoping.(2017).Synthesis and flame retardant properties of phosphorus hybrid monomer VOPP grafted polystyrene copolymer.Fuhe Cailiao Xuebao/Acta Materiae Compositae Sinica,34(10),2141-2149. |
MLA | Cui, Jinfeng,et al."Synthesis and flame retardant properties of phosphorus hybrid monomer VOPP grafted polystyrene copolymer".Fuhe Cailiao Xuebao/Acta Materiae Compositae Sinica 34.10(2017):2141-2149. |
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