Effect of surface dispersants on nano-copper powders prepared by electrochemical method
Xu, Jian-Lin1,2; Chen, Ji-Dong3; Wang, Zhi-Ping1,2; Ran, Fen1,2; Yang, Shu-Hua1,2
2011-02-01
发表期刊Cailiao Kexue yu Gongyi/Material Science and Technology
ISSN10050299
卷号19期号:1页码:116-120
摘要To research the effect of surface dispersants on nano-copper powders, taking sodium dodecyl sulfate, Tween20, Tween40, Tween80 and their composites as surface dispersants, some nano-copper powders with different particle shape and size were prepared by electrochemical method. The phases of nano-copper powders were analyzed by XRD and FT-IR, and the morphology and particle size were analyzed by TEM. The results show that different surface dispersants play different role in the preparing process of the nano-copper powders. The sodium dodecyl sulfate can prevent the powder from oxidation due to electrostatic attraction of double electricity layer and steric barrier effect. Tweens can control the powders aggregation accompanied with higher steric barrier effect, of which the Tween -80 has the best effect. However, the resulting nano-copper powders can be oxidized and aggregated during electrochemical processing with single surface dispersant. When the sodium dodecyl sulfate and Tween80 are used together, the resulting nano-copper with particle size of 20~50 nm can be obtained by electrochemical method, because stronger electrostatic attraction of double electricity layer of sodium dodecyl sulfate and higher steric barrier effect can prevent the powders from oxidation and aggregation.
关键词Agglomeration Copper powder Electrostatics Morphology Oxidation Particle size Sulfur compounds Dispersants Electrochemical ELectrochemical methods Electrochemical processing Electrostatic attractions Nano copper powder Particle shape and size Preparing process
收录类别EI
语种中文
出版者Harbin Institute of Technology
EI入藏号20111813953433
EI主题词Sodium dodecyl sulfate
EI分类号544.1 Copper - 701.1 Electricity: Basic Concepts and Phenomena - 802.2 Chemical Reactions - 802.3 Chemical Operations - 803 Chemical Agents and Basic Industrial Chemicals - 804 Chemical Products Generally - 951 Materials Science
来源库Compendex
分类代码544.1 Copper - 701.1 Electricity: Basic Concepts and Phenomena - 802.2 Chemical Reactions - 802.3 Chemical Operations - 803 Chemical Agents and Basic Industrial Chemicals - 804 Chemical Products Generally - 951 Materials Science
文献类型期刊论文
条目标识符https://ir.lut.edu.cn/handle/2XXMBERH/111575
专题材料科学与工程学院
省部共建有色金属先进加工与再利用国家重点实验室
作者单位1.State Key Laboratory of Gansu Advanced Non-ferrous Metal Materials, Lanzhou University of Technology, Lanzhou 730050, China;
2.Key Laboratory of Non-ferrous Metal Alloys and Processing, The Ministry of Education, Lanzhou University of Technology, Lanzhou 730050, China;
3.Shaoxing Testing Institute of Quality Technical Supervision, Shaoxing 312017, China
第一作者单位省部共建有色金属先进加工与再利用国家重点实验室;  兰州理工大学
第一作者的第一单位省部共建有色金属先进加工与再利用国家重点实验室
推荐引用方式
GB/T 7714
Xu, Jian-Lin,Chen, Ji-Dong,Wang, Zhi-Ping,et al. Effect of surface dispersants on nano-copper powders prepared by electrochemical method[J]. Cailiao Kexue yu Gongyi/Material Science and Technology,2011,19(1):116-120.
APA Xu, Jian-Lin,Chen, Ji-Dong,Wang, Zhi-Ping,Ran, Fen,&Yang, Shu-Hua.(2011).Effect of surface dispersants on nano-copper powders prepared by electrochemical method.Cailiao Kexue yu Gongyi/Material Science and Technology,19(1),116-120.
MLA Xu, Jian-Lin,et al."Effect of surface dispersants on nano-copper powders prepared by electrochemical method".Cailiao Kexue yu Gongyi/Material Science and Technology 19.1(2011):116-120.
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