Preparation of biochar adsorbent from straw and its adsorption capability
Zhang, Jiyi1; Pu, Lijun1; Li, Gen2
2011-12-01
发表期刊Nongye Gongcheng Xuebao/Transactions of the Chinese Society of Agricultural Engineering
ISSN10026819
卷号27期号:SUPPL.2页码:104-109
摘要In order to find a new way of using discarded biomass materials, the wheat straw was used to prepare biochar adsorbent by means of carbonization at low and middle temperatures. Then, the Cu2+ was taken as adsorbed substance to investigate the biochar adsorbent adsorption capability for heavy metal from the wastewater. The results showed that the biochar adsorbent prepared at low and middle temperatures (200-500°C) obtained higher productivity with less energy consumption, easier process, higher adsorption speed and short time to reach the adsorption equilibrium. At the same time, it was found that the longest time to reach the adsorption equilibrium was 3 h (P200), and the shortest time was just only 0.5 h (P500). The maximum adsorption capacity of P500 could reach to 11.19 mg/g at 30°C. The adsorption kinetic process was consistent with the Lagergren pseudo-second order kinetic model. The adsorption isotherm agreed well with the Langmuir formulae, and the separation factor (RL) located in the range of 0-1 for favored adsorption. The SEM results indicated that the pore deformation and the straw roughness increased as the carbonization temperature rising, which made the pore canal effect easier and the adsorption properties more excellent. The research can provide a reference for engineering application of biomass adsorbent.
关键词Adsorption isotherms Carbonization Copper Energy utilization Heavy metals Isotherms Straw Adsorption capability Adsorption equilibria Adsorption properties Biochar adsorbents Carbonization temperatures Engineering applications Preparation Pseudo-second-order kinetic models
DOI10.3969/j.issn.1002-6819.2011.z2.021
收录类别EI
语种中文
出版者Chinese Society of Agricultural Engineering
EI入藏号20121314900339
EI主题词Adsorption
EI分类号525.3 Energy Utilization - 531 Metallurgy and Metallography - 544.1 Copper - 802.2 Chemical Reactions - 802.3 Chemical Operations - 821.5 Agricultural Wastes
来源库Compendex
分类代码525.3 Energy Utilization - 531 Metallurgy and Metallography - 544.1 Copper - 802.2 Chemical Reactions - 802.3 Chemical Operations - 821.5 Agricultural Wastes
引用统计
文献类型期刊论文
条目标识符https://ir.lut.edu.cn/handle/2XXMBERH/111313
专题石油化工学院
作者单位1.College of Petrochemical Engineering, Lanzhou University of Technology, Lanzhou 730050, China;
2.Cscec Aecom Consultants Co. Ltd., Lanzhou 730000, China
第一作者单位兰州理工大学
第一作者的第一单位兰州理工大学
推荐引用方式
GB/T 7714
Zhang, Jiyi,Pu, Lijun,Li, Gen. Preparation of biochar adsorbent from straw and its adsorption capability[J]. Nongye Gongcheng Xuebao/Transactions of the Chinese Society of Agricultural Engineering,2011,27(SUPPL.2):104-109.
APA Zhang, Jiyi,Pu, Lijun,&Li, Gen.(2011).Preparation of biochar adsorbent from straw and its adsorption capability.Nongye Gongcheng Xuebao/Transactions of the Chinese Society of Agricultural Engineering,27(SUPPL.2),104-109.
MLA Zhang, Jiyi,et al."Preparation of biochar adsorbent from straw and its adsorption capability".Nongye Gongcheng Xuebao/Transactions of the Chinese Society of Agricultural Engineering 27.SUPPL.2(2011):104-109.
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