Thiol and thioether removal from RFCC gasoline with attapulgite clay

doi:10.3969/j.issn.0438-1157.2012.01.041

IR > 石油化工学院

	Thiol and thioether removal from RFCC gasoline with attapulgite clay
	Wang, Qingning 1; Zhang, Zhengcai 1; Xie, Zhenping 1; Wu, Yingqin 2; Li, Lan1 ; Jiao, Linhong 1
	2012
发表期刊	Huagong Xuebao/CIESC Journal
ISSN	04381157
卷号	63 期号:1 页码:292-300
摘要	One of main pollutants in air is sulfur oxides that comes from the combustion of coal and transportation fuels. There are some regulations or rules in many countries, which set the level of sulfur content in transportation fuels, so it becomes urgent to do ultra-deep desulfurization. Hydro-desulfurization process is usually used in petroleum refining industry, in which compounds containing-sulfur are converted to H2S removed in high temperature and high hydrogen pressure. However it is difficult for removing aromatic heterocyclic sulfur. So, alterative technologies have been developed, such as adsorptive-, oxidative- and bio-desulfurization. In this paper a desulfurization agent for residue fluid catalytic cracking gasoline(RFCCG) was prepared by impregnation technique. The compounds of transition metals(Fe, Cu) were used as active component and the attapulgite, treated with nitric acid, as carrier. The sulfur content in RFCCG was analyzed by gas chromatography with atomic emission detection(GC-AED). The desulfurization agent was characterized by fourier transform infrared spectrometer(FTIR), X-ray diffraction(XRD), BET and X-ray photoelectron spectroscopy(XPS). The parameters of desulfurization process for the agent were optimized by experimental study designed by the orthogonal test. The results indicated that the best desulfurization agent obtained are 7% Fe and 6% Cu compounds on attapulgite which was acidulated and roasted at 450°C for 5 h. The desulfurization rate was 70.02% at atmosphere pressure and room temperature, and sulfur content in RFCCG reduced from 804 μg·g-1 to 241 μg·g-1. © All Rights Reserved.
关键词	Coal combustion Coal transportation Copper compounds Fourier transform infrared spectroscopy Gas chromatography Gasoline Hydrodesulfurization Petroleum industry Petroleum refining Spectrometers Transition metals X ray photoelectron spectroscopy Atomic emission detection Attapulgite clay De-sulfurization process Fourier transform infrared spectrometer High hydrogen pressure Immersion method Thioethers Thiol
DOI	10.3969/j.issn.0438-1157.2012.01.041
收录类别	EI
语种	中文
出版者	Chemical Industry Press
EI入藏号	20120814790377
EI主题词	Fluid catalytic cracking
EI分类号	503 Mines and Mining, Coal - 513.1 Petroleum Refining, General - 521 Fuel Combustion and Flame Research - 523 Liquid Fuels - 524 Solid Fuels - 531 Metallurgy and Metallography - 741.3 Optical Devices and Systems - 801 Chemistry - 802.2 Chemical Reactions - 802.3 Chemical Operations
来源库	Compendex
分类代码	503 Mines and Mining, Coal - 513.1 Petroleum Refining, General - 521 Fuel Combustion and Flame Research - 523 Liquid Fuels - 524 Solid Fuels - 531 Metallurgy and Metallography - 741.3 Optical Devices and Systems - 801 Chemistry - 802.2 Chemical Reactions - 802.3 Chemical Operations
引用统计	无
文献类型	期刊论文
条目标识符	https://ir.lut.edu.cn/handle/2XXMBERH/111183
专题	石油化工学院
作者单位	1.School of Petrochemical Engineering, Lanzhou University of Technology, Lanzhou 730050, Gansu, China; 2.Key Laboratory of Gas Geochemistry, Institute of Geology and Geophysics, CAS, Lanzhou 730000, Gansu, China
第一作者单位	兰州理工大学
第一作者的第一单位	兰州理工大学
推荐引用方式 GB/T 7714	Wang, Qingning,Zhang, Zhengcai,Xie, Zhenping,et al. Thiol and thioether removal from RFCC gasoline with attapulgite clay[J]. Huagong Xuebao/CIESC Journal,2012,63(1):292-300.
APA	Wang, Qingning,Zhang, Zhengcai,Xie, Zhenping,Wu, Yingqin,Li, Lan,&Jiao, Linhong.(2012).Thiol and thioether removal from RFCC gasoline with attapulgite clay.Huagong Xuebao/CIESC Journal,63(1),292-300.
MLA	Wang, Qingning,et al."Thiol and thioether removal from RFCC gasoline with attapulgite clay".Huagong Xuebao/CIESC Journal 63.1(2012):292-300.