Facile synthesis of microporous carbon for supercapacitors with a LiNO3 electrolyte | |
Luo, HeMing; Yang, YanFei; Mu, Bo; Chen, YanZheng; Zhang, JianQiang; Zhao, Xia | |
2016-04 | |
发表期刊 | CARBON |
ISSN | 0008-6223 |
卷号 | 100页码:214-222 |
摘要 | A facile method for the direct synthesis of interconnected microporous carbon via carbonization of potassium acid phthalate in inert atmosphere is reported. The as-obtained microporous carbon exhibited a high specific surface area (1118 m(2) g(-1)) and 67% of the pore volume was attributed to microporosity, which are ideal for electrodes of supercapacitors. LiNO3 electrolytes of different concentrations were selected according to their corresponding conductivities to evaluate the use of aqueous electrolytes in supercapacitors. The electrochemical performance of the interconnected microporous carbon in 6 M KOH and 1-5 M LiNO3 electrolytes was investigated. The results showed that the microporous carbon could deliver optimal electrochemical properties as an electrode material for supercapacitors. In addition, the electrochemical investigation showed that the microporous carbon exhibited a broad voltage operational window in 3 M LiNO3 electrolyte. Furthermore, 86.2% of the capacitance was retained even after 5000 cycles at 1.6 V. (C) 2016 Elsevier Ltd. All rights reserved. |
关键词 | Capacitance Carbon Carbonization Electrochemical electrodes Electrolytes Electrolytic capacitors Microporosity Potassium hydroxide Supercapacitor Aqueous electrolyte Electrochemical investigations Electrochemical performance Electrode material High specific surface area Micro-porous carbons Operational windows Potassium acid phthalate |
DOI | 10.1016/j.carbon.2016.01.004 |
收录类别 | SCI ; SCIE |
语种 | 英语 |
资助项目 | National Natural Science Foundation of China (NSFC)[21364004] |
WOS研究方向 | Chemistry ; Materials Science |
WOS类目 | Chemistry, Physical ; Materials Science, Multidisciplinary |
WOS记录号 | WOS:000369961400026 |
出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
EI入藏号 | 20160801971891 |
EI主题词 | Lithium compounds |
EI分类号 | 701.1 Electricity: Basic Concepts and Phenomena - 704.1 Electric Components - 802.2 Chemical Reactions - 804 Chemical Products Generally - 804.2 Inorganic Compounds - 931.2 Physical Properties of Gases, Liquids and Solids |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | https://ir.lut.edu.cn/handle/2XXMBERH/33729 |
专题 | 石油化工学院 工会 |
通讯作者 | Luo, HeMing |
作者单位 | Lanzhou Univ Technol, Coll Petrochem Technol, Lanzhou 730050, Peoples R China |
第一作者单位 | 石油化工学院 |
通讯作者单位 | 石油化工学院 |
第一作者的第一单位 | 石油化工学院 |
推荐引用方式 GB/T 7714 | Luo, HeMing,Yang, YanFei,Mu, Bo,et al. Facile synthesis of microporous carbon for supercapacitors with a LiNO3 electrolyte[J]. CARBON,2016,100:214-222. |
APA | Luo, HeMing,Yang, YanFei,Mu, Bo,Chen, YanZheng,Zhang, JianQiang,&Zhao, Xia.(2016).Facile synthesis of microporous carbon for supercapacitors with a LiNO3 electrolyte.CARBON,100,214-222. |
MLA | Luo, HeMing,et al."Facile synthesis of microporous carbon for supercapacitors with a LiNO3 electrolyte".CARBON 100(2016):214-222. |
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