Facile synthesis of microporous carbon for supercapacitors with a LiNO3 electrolyte
Luo, HeMing; Yang, YanFei; Mu, Bo; Chen, YanZheng; Zhang, JianQiang; Zhao, Xia
2016-04
发表期刊CARBON
ISSN0008-6223
卷号100页码:214-222
摘要A facile method for the direct synthesis of interconnected microporous carbon via carbonization of potassium acid phthalate in inert atmosphere is reported. The as-obtained microporous carbon exhibited a high specific surface area (1118 m(2) g(-1)) and 67% of the pore volume was attributed to microporosity, which are ideal for electrodes of supercapacitors. LiNO3 electrolytes of different concentrations were selected according to their corresponding conductivities to evaluate the use of aqueous electrolytes in supercapacitors. The electrochemical performance of the interconnected microporous carbon in 6 M KOH and 1-5 M LiNO3 electrolytes was investigated. The results showed that the microporous carbon could deliver optimal electrochemical properties as an electrode material for supercapacitors. In addition, the electrochemical investigation showed that the microporous carbon exhibited a broad voltage operational window in 3 M LiNO3 electrolyte. Furthermore, 86.2% of the capacitance was retained even after 5000 cycles at 1.6 V. (C) 2016 Elsevier Ltd. All rights reserved.
关键词Capacitance Carbon Carbonization Electrochemical electrodes Electrolytes Electrolytic capacitors Microporosity Potassium hydroxide Supercapacitor Aqueous electrolyte Electrochemical investigations Electrochemical performance Electrode material High specific surface area Micro-porous carbons Operational windows Potassium acid phthalate
DOI10.1016/j.carbon.2016.01.004
收录类别SCI ; SCIE
语种英语
资助项目National Natural Science Foundation of China (NSFC)[21364004]
WOS研究方向Chemistry ; Materials Science
WOS类目Chemistry, Physical ; Materials Science, Multidisciplinary
WOS记录号WOS:000369961400026
出版者PERGAMON-ELSEVIER SCIENCE LTD
EI入藏号20160801971891
EI主题词Lithium compounds
EI分类号701.1 Electricity: Basic Concepts and Phenomena - 704.1 Electric Components - 802.2 Chemical Reactions - 804 Chemical Products Generally - 804.2 Inorganic Compounds - 931.2 Physical Properties of Gases, Liquids and Solids
引用统计
被引频次:30[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符https://ir.lut.edu.cn/handle/2XXMBERH/33729
专题石油化工学院
工会
通讯作者Luo, HeMing
作者单位Lanzhou Univ Technol, Coll Petrochem Technol, Lanzhou 730050, Peoples R China
第一作者单位石油化工学院
通讯作者单位石油化工学院
第一作者的第一单位石油化工学院
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GB/T 7714
Luo, HeMing,Yang, YanFei,Mu, Bo,et al. Facile synthesis of microporous carbon for supercapacitors with a LiNO3 electrolyte[J]. CARBON,2016,100:214-222.
APA Luo, HeMing,Yang, YanFei,Mu, Bo,Chen, YanZheng,Zhang, JianQiang,&Zhao, Xia.(2016).Facile synthesis of microporous carbon for supercapacitors with a LiNO3 electrolyte.CARBON,100,214-222.
MLA Luo, HeMing,et al."Facile synthesis of microporous carbon for supercapacitors with a LiNO3 electrolyte".CARBON 100(2016):214-222.
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