Nitrogen-self-doped mesoporous carbons synthesized by the direct carbonization of ferric ammonium citrate for high-performance supercapacitors | |
Luo, Heming; Chen, YanZheng; wang, Bing; Zhang, Jianqiang; Zhao, Xia; Mu, Bo | |
2017-02 | |
发表期刊 | JOURNAL OF SOLID STATE ELECTROCHEMISTRY |
ISSN | 1432-8488 |
卷号 | 21期号:2页码:515-524 |
摘要 | We report a simple method of synthesizing nitrogen-self-doped mesoporous carbons by the direct carbonization of ferric ammonium citrate (FAC) in an inert atmosphere. The resulting materials stacked by nanospherical particles exhibited a large the Brunauer-Emmett-Teller (BET) surface area of up to 1021 m(2) g(-1), bimodal porosity (pores centered at approximately 2 and 9 nm), and nitrogen self doping (3.86 %). The electrochemical properties of the nitrogen-self-doped mesoporous carbons were evaluated in 1 M H2SO4 aqueous solutions by cyclic voltammetry (CV), galvanostatic charge/discharge (GCD), and electrochemical impedance spectroscopy (EIS). Results showed that FBNC-700 (FB represents FAC brown (CAS Reg. No. 1332-98-5), N represents "nitrogen-self-doped," C represents mesoporous-carbon materials, and 700 represents carbonization temperature), as an electrode for supercapacitors, exhibited a high specific capacitance of 225 F g(-1) at a current density of 1 A g(-1). This specific capacitance may be maintained at 162 F g(-1) and 10 A g(-1). The pair of oxidation and reduction peaks at approximately 0.4 V (quinone-type species (C = O)) was broad and extended to lower potentials (down to 0 V; N functionalities), indicating the excellent pseudocapacitive behavior of nitrogen-self-doped mesoporous carbons. The nitrogen-self-doped mesoporous carbons had good stability, with 93.92 % capacitance retention after 5000 cycles at a current density of 2 A g(-1). |
关键词 | Ferric ammonium citrate Mesoporous carbon Self nitrogen doped Supercapacitor |
DOI | 10.1007/s10008-016-3386-1 |
收录类别 | SCI ; SCIE |
语种 | 英语 |
资助项目 | Provincial Natural Science Foundation of Gansu[1506RJZA102] |
WOS研究方向 | Electrochemistry |
WOS类目 | Electrochemistry |
WOS记录号 | WOS:000394162400021 |
出版者 | SPRINGER |
EI入藏号 | 20163902851942 |
EI主题词 | Mesoporous materials |
EI分类号 | 701.1 Electricity: Basic Concepts and Phenomena - 801 Chemistry - 801.4.1 Electrochemistry - 802.2 Chemical Reactions - 804 Chemical Products Generally |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | https://ir.lut.edu.cn/handle/2XXMBERH/33371 |
专题 | 石油化工学院 |
通讯作者 | Mu, Bo |
作者单位 | Lanzhou Univ Technol, Coll Petrochem Technol, Lanzhou 730050, Peoples R China |
第一作者单位 | 石油化工学院 |
通讯作者单位 | 石油化工学院 |
第一作者的第一单位 | 石油化工学院 |
推荐引用方式 GB/T 7714 | Luo, Heming,Chen, YanZheng,wang, Bing,et al. Nitrogen-self-doped mesoporous carbons synthesized by the direct carbonization of ferric ammonium citrate for high-performance supercapacitors[J]. JOURNAL OF SOLID STATE ELECTROCHEMISTRY,2017,21(2):515-524. |
APA | Luo, Heming,Chen, YanZheng,wang, Bing,Zhang, Jianqiang,Zhao, Xia,&Mu, Bo.(2017).Nitrogen-self-doped mesoporous carbons synthesized by the direct carbonization of ferric ammonium citrate for high-performance supercapacitors.JOURNAL OF SOLID STATE ELECTROCHEMISTRY,21(2),515-524. |
MLA | Luo, Heming,et al."Nitrogen-self-doped mesoporous carbons synthesized by the direct carbonization of ferric ammonium citrate for high-performance supercapacitors".JOURNAL OF SOLID STATE ELECTROCHEMISTRY 21.2(2017):515-524. |
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