Preparation of metal-organic framework-derived porous carbon and study of its supercapacitive performance | |
Zhang, Jianqiang; Xue, Jiechen; Li, Ping; Huang, Siyun; Feng, Huixia; Luo, Heming | |
2018-09-10 | |
发表期刊 | ELECTROCHIMICA ACTA |
ISSN | 0013-4686 |
卷号 | 284页码:328-335 |
摘要 | Metal-organic frameworks are formed via the connection of transition metals with oxygen-or nitrogencontaining organic ligands; the organic ligands are rich in carbon and contain heteroatoms such as N and P. Herein, NMFC-T porous carbon was prepared with (Ni-3(BTC)(2)(Me2NH)(3)) as the carbon precursor using the strategy of pre-carbonization and KOH activation. Influence of carbonization temperature on properties of NMFC-T porous carbon was investigated, and the electrochemical performance of NMFC-800 porous carbon was studied using a three-electrode system. Results revealed that NMFC-800 porous carbon has a high specific surface area of 1143 m(2)g(-1) with a mesopore proportion over 80%. Using KOH solution as an electrolyte, the specific capacitance was as high as 211 F g(-1) at a current density of 1 A g(-1), and the capacitance retention was 81.04% after 5000 cycles. NMFC-800 porous carbon has excellent supercapacitive performance and good cycle stability. (C) 2018 Elsevier Ltd. All rights reserved. |
关键词 | Metal-organic frameworks Activation Porous carbon Specific capacitance |
DOI | 10.1016/j.electacta.2018.07.102 |
收录类别 | SCI ; SCIE |
语种 | 英语 |
资助项目 | National Nature Science Foundation of China[21364004][21664009] |
WOS研究方向 | Electrochemistry |
WOS类目 | Electrochemistry |
WOS记录号 | WOS:000442485100037 |
出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
EI入藏号 | 20183105637618 |
EI主题词 | Carbon |
EI分类号 | 531 Metallurgy and Metallography - 701.1 Electricity: Basic Concepts and Phenomena - 801.4 Physical Chemistry - 802.2 Chemical Reactions - 804 Chemical Products Generally - 815.1.1 Organic Polymers - 951 Materials Science |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | https://ir.lut.edu.cn/handle/2XXMBERH/32456 |
专题 | 石油化工学院 土木工程学院 教务处(创新创业学院) |
通讯作者 | Luo, Heming |
作者单位 | LanZhou Univ Technol, Sch Petrochem Engn, Lanzhou 730050, Gansu, Peoples R China |
第一作者单位 | 兰州理工大学 |
通讯作者单位 | 兰州理工大学 |
第一作者的第一单位 | 兰州理工大学 |
推荐引用方式 GB/T 7714 | Zhang, Jianqiang,Xue, Jiechen,Li, Ping,et al. Preparation of metal-organic framework-derived porous carbon and study of its supercapacitive performance[J]. ELECTROCHIMICA ACTA,2018,284:328-335. |
APA | Zhang, Jianqiang,Xue, Jiechen,Li, Ping,Huang, Siyun,Feng, Huixia,&Luo, Heming.(2018).Preparation of metal-organic framework-derived porous carbon and study of its supercapacitive performance.ELECTROCHIMICA ACTA,284,328-335. |
MLA | Zhang, Jianqiang,et al."Preparation of metal-organic framework-derived porous carbon and study of its supercapacitive performance".ELECTROCHIMICA ACTA 284(2018):328-335. |
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