Synthesis of nickel phosphide nanorods for hydrotreating reactions | |
Zhao, Yu1; Wang, Shidong1; Li, Ning1; Zhang, Qi1; Li, Guixian1; Shen, Jianyi2 | |
2019-05-05 | |
发表期刊 | CATALYSIS COMMUNICATIONS |
ISSN | 1566-7367 |
卷号 | 124页码:67-70 |
摘要 | Nickel phosphate (NiPO) nanofibers with high surface area (288 m(2)/g) were obtained from phosphoric acid and nickel nitrate in an ionic liquid ([Bmim]Br) via an ionothermal synthesis process at 150 degrees C. Heating the nano fibers under a H-2 atmosphere at 700 degrees C led to the formation of Ni2P nanorods, similar to 50 nm in diameter and 100-200 nm in length. The Ni2P nanorod catalyst exhibited a much higher turnover frequency in the hydrodesulfurization of dibenzothiophene than the previously reported Ni2P catalysts with nanoparticle, nanosheet or irregular block morphologies, which may be attributable to the morphology effect of the nanorods. |
关键词 | Nickel phosphate nanofibers Ionothermal synthesis Ni2P nanorods Hydrotreating reactions |
DOI | 10.1016/j.catcom.2019.03.006 |
收录类别 | SCI ; SCIE |
语种 | 英语 |
资助项目 | National Natural Science Foundation of China[21203081][21763016] ; Natural Science Foundation of Gansu Province[18YF1GA062][2017GS10924] |
WOS研究方向 | Chemistry |
WOS类目 | Chemistry, Physical |
WOS记录号 | WOS:000464482500013 |
出版者 | ELSEVIER SCIENCE BV |
EI入藏号 | 20191006604600 |
EI主题词 | Nickel compounds |
EI分类号 | 761 Nanotechnology - 802.3 Chemical Operations - 804 Chemical Products Generally - 933 Solid State Physics - 951 Materials Science |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | https://ir.lut.edu.cn/handle/2XXMBERH/31870 |
专题 | 石油化工学院 法学院 |
通讯作者 | Zhao, Yu |
作者单位 | 1.Lanzhou Univ Technol, Sch Petrochem Engn, Lanzhou 730050, Gansu, Peoples R China; 2.Nanjing Univ, Sch Chem & Chem Engn, Nanjing 210093, Jiangsu, Peoples R China |
第一作者单位 | 兰州理工大学 |
通讯作者单位 | 兰州理工大学 |
第一作者的第一单位 | 兰州理工大学 |
推荐引用方式 GB/T 7714 | Zhao, Yu,Wang, Shidong,Li, Ning,et al. Synthesis of nickel phosphide nanorods for hydrotreating reactions[J]. CATALYSIS COMMUNICATIONS,2019,124:67-70. |
APA | Zhao, Yu,Wang, Shidong,Li, Ning,Zhang, Qi,Li, Guixian,&Shen, Jianyi.(2019).Synthesis of nickel phosphide nanorods for hydrotreating reactions.CATALYSIS COMMUNICATIONS,124,67-70. |
MLA | Zhao, Yu,et al."Synthesis of nickel phosphide nanorods for hydrotreating reactions".CATALYSIS COMMUNICATIONS 124(2019):67-70. |
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