Synthesis and self-assembly of chalcone-based organogels | |
Zhang, Ying-Peng; Wang, Bao-Xu; Yang, Yun-Shang; Liang, Chuan; Yang, Chen; Hong-Li Chai | |
2019-09-20 | |
发表期刊 | COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS |
ISSN | 0927-7757 |
卷号 | 577页码:449-455 |
摘要 | Five naphthalene-type chalcone organogelators with different hydrophobic alkyl units, were designed and synthesized. The prepared organogelators demonstrated excellent gel properties in some selected solvents, such as cyclohexane, tert-Butanol, isooctane, and isopropanol etc. The results for thermal stability showed that the alkyl chain length attached to the chalcone also had an important influence on the gelation behavior. Under identical concentrations increasing the length of alkyl chains of the gel molecules and then the gel-to-sol transition temperature value is increased too. It has found that the hydrogen bonding between molecules, the van der Waals force and the pi-pi stacking provide multiple driving forces for gel self-assembly using various techniques. The morphology of the xerogel was investigated by Scanning Electron Microscope (SEM). As the length of the carbon chain increases, the dry gel tends to form a lamellar network structure. The UV-vis absorption and emission spectra of the gel molecules were also studied. |
关键词 | Naphthalene Chalcone Organogels Alkyl chains Self-assembly |
DOI | 10.1016/j.colsurfa.2019.06.010 |
收录类别 | SCI ; SCIE |
语种 | 英语 |
WOS研究方向 | Chemistry |
WOS类目 | Chemistry, Physical |
WOS记录号 | WOS:000477008000051 |
出版者 | ELSEVIER |
EI入藏号 | 20192507066946 |
EI主题词 | Naphthalene |
EI分类号 | 801.4 Physical Chemistry - 802.3 Chemical Operations - 804 Chemical Products Generally - 804.1 Organic Compounds - 931.3 Atomic and Molecular Physics - 951 Materials Science |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | https://ir.lut.edu.cn/handle/2XXMBERH/31563 |
专题 | 石油化工学院 |
通讯作者 | Zhang, Ying-Peng; Yang, Yun-Shang |
作者单位 | Lanzhou Univ Technol, Sch Petrochem Engn, Lanzhou 730050, Gansu, Peoples R China |
第一作者单位 | 兰州理工大学 |
通讯作者单位 | 兰州理工大学 |
第一作者的第一单位 | 兰州理工大学 |
推荐引用方式 GB/T 7714 | Zhang, Ying-Peng,Wang, Bao-Xu,Yang, Yun-Shang,et al. Synthesis and self-assembly of chalcone-based organogels[J]. COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS,2019,577:449-455. |
APA | Zhang, Ying-Peng,Wang, Bao-Xu,Yang, Yun-Shang,Liang, Chuan,Yang, Chen,&Hong-Li Chai.(2019).Synthesis and self-assembly of chalcone-based organogels.COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS,577,449-455. |
MLA | Zhang, Ying-Peng,et al."Synthesis and self-assembly of chalcone-based organogels".COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS 577(2019):449-455. |
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