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Toughening modification of epoxy resins by epoxy-terminated hyperbranched polyethers fabricated by doping sorbitol with inositol
Lu, Siyuan1,2; Wu, Gang1,2; Niu, Fangfang1,2; Liu, Yangdong1,2; Liu, Xingsheng1,2; Xu, Wan1,2; Chen, Zhenbin1,2,3
2023-08-14
Early Access Date2023-08
Source PublicationJOURNAL OF APPLIED POLYMER SCIENCE
ISSN0021-8995 ; 1097-4628
AbstractIncreasing social awareness concerning the design of excellent performance toughening agents to curb the adverse effects of insufficient toughness on the wide range of applications of epoxy resin (EP). Herein, a small amount of sorbitol was doped into carbocyclic inositol as a core monomer, and bisphenol-A and epichlorohydrin were used to produce epoxide-terminated hyperbranched polyether by one-pot preparation method. After that, the prepared polymer was used as modifier to improve the toughness and strength of petroleum-based EPs. Results demonstrated that after adding the homemade epoxy-terminated hyperbranched polyether (EHBPE) to the EP, the polyether prepared with the ratio of sorbitol and inositol displayed significant advantages compared with the polyether with monomers using only sorbitol and inositol, respectively. In particular, the impact, and tensile strengths of EHBPE-IS/EP cured sample with EHBPE-IS loading at 20% were increased by 197.5%, 139.6%, respectively, compared with those of neat EP. In brief, EHBPE-IS, a member of the family of EHBPEs, provided a facile method for the preparation of bifunctional modifier for tough and strong EP with promising industrial applications.
Keywordepoxy-terminated hyperbranched polyether inositol mechanical properties mechanisms sorbitol
DOI10.1002/app.54551
Indexed BySCIE ; EI
Language英语
WOS Research AreaPolymer Science
WOS SubjectPolymer Science
WOS IDWOS:001048511700001
PublisherWILEY
EI Accession Number20233414583870
EI KeywordsEpoxy resins
EI Classification Number804 Chemical Products Generally ; 804.1 Organic Compounds ; 815.1.1 Organic Polymers
Original literature typeArticle;Early Access
Citation statistics
Cited Times [WOS]:0   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttps://ir.lut.edu.cn/handle/2XXMBERH/166173
Collection理学院
材料科学与工程学院
Corresponding AuthorChen, Zhenbin
Affiliation1.Lanzhou Univ Technol, State Key Lab Gansu Adv Nonferrous Met Mat, Lanzhou, Peoples R China;
2.Lanzhou Univ Technol, Sch Mat Sci & Engn, Lanzhou, Peoples R China;
3.Lanzhou Univ Technol, Sch Mat Sci & Engn, State Key Lab Adv Progressing & Recycling Nonferro, Lanzhou, Peoples R China
First Author AffilicationState Key Laboratory Of Gansu Advanced Non-Ferrous Metal Materials;  Coll Mat Sci & Engn
Corresponding Author AffilicationState Key Laboratory Of Gansu Advanced Non-Ferrous Metal Materials;  Coll Mat Sci & Engn
First Signature AffilicationState Key Laboratory Of Gansu Advanced Non-Ferrous Metal Materials
Recommended Citation
GB/T 7714
Lu, Siyuan,Wu, Gang,Niu, Fangfang,et al. Toughening modification of epoxy resins by epoxy-terminated hyperbranched polyethers fabricated by doping sorbitol with inositol[J]. JOURNAL OF APPLIED POLYMER SCIENCE,2023.
APA Lu, Siyuan.,Wu, Gang.,Niu, Fangfang.,Liu, Yangdong.,Liu, Xingsheng.,...&Chen, Zhenbin.(2023).Toughening modification of epoxy resins by epoxy-terminated hyperbranched polyethers fabricated by doping sorbitol with inositol.JOURNAL OF APPLIED POLYMER SCIENCE.
MLA Lu, Siyuan,et al."Toughening modification of epoxy resins by epoxy-terminated hyperbranched polyethers fabricated by doping sorbitol with inositol".JOURNAL OF APPLIED POLYMER SCIENCE (2023).
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