Lanzhou University of Technology Institutional Repository （LUT_IR）
| Building rapid charge transfer channel via engineering Ni coordinated flexible polymer for efficient solar hydrogen evolution | |
| Zhang, Yiming1,2,3,4; Wang, Xusheng5; Ren, Xiaohui2,6; Luo, Shunqin2,8; Huang, Hengming2; Chen, Rongsheng6; Shao, Shibo7; Liu, Dan3,4; Gao, Junkuo5; Gui, Jianzhou3,4 | |
| 2023-01-15 | |
| Source Publication | CHEMICAL ENGINEERING JOURNAL
 |
| ISSN | 1385-8947 |
| Volume | 456 |
| Abstract | Building rapid charge transfer channel from photocatalysts to cocatalysts can greatly improve the photocatalytic performance, yet remains a grand challenge. In this work, a flexible polymer engineering strategy was utilized to fabricate a homogeneous conductive N-doped carbon (NC) layer between CdS photo-absorber and surface NiO cocatalyst. The detailed formation procedure of NC layers was unraveled by a series of in-situ and ex-situ temperature-dependent analysis. Such a bifunctional layer can serve as not only a rapid charge transfer chan-nel for photo-induced charge carriers, but also modulate the adsorption of H on NiO cocatalyst for concertedly boosting solar hydrogen production performance (101.92 mmol h-1 g-1). The DFT calculation together with SI-XPS, PL, TRPL, EIS and photocurrent plots indicated that the generated built-in electric field with the direction from NiO nanoparticles to NC layers could accelerate the excited electrons transfer to active sites. Furthermore, the adsorption and desorption energy of hydrogen on NiO nanoparticles was also optimized by the NC layers, as verified by DFT calculation. This work provides new insights into interfacial engineering between catalysts and cocatalysts for highly efficient photocatalysis. |
| Keyword | Flexible polymer N-doped carbon Engineering Charge transfer channel Photocatalytic |
| DOI | 10.1016/j.cej.2022.141032 |
| Indexed By | SCIE |
| Language | 英语 |
| WOS Research Area | Engineering |
| WOS Subject | Engineering, Environmental ; Engineering, Chemical |
| WOS ID | WOS:000909955100001 |
| Publisher | ELSEVIER SCIENCE SA |
| Document Type | 期刊论文 |
| Identifier | https://ir.lut.edu.cn/handle/2XXMBERH/161032 |
| Collection | 兰州理工大学 |
| Affiliation | 1.Lanzhou Univ Technol, Sch Mat Sci & Engn, State Key Lab Adv Proc & Recycling Nonferrous Met, Lanzhou 730050, Peoples R China; 2.Natl Inst Mat Sci NIMS, Int Ctr Mat Nanoarchitecton WPI MANA, 1 1 Namiki, Tsukuba, Ibaraki 3050044, Japan; 3.Tiangong Univ, State Key Lab Separat Membranes & Membrane Proc, Tianjin Key Lab Green Chem Technol & Proc Engn, Tianjin 300387, Peoples R China; 4.Tiangong Univ, Sch Chem Engn & Technol, Tianjin 300387, Peoples R China; 5.Zhejiang Sci Tech Univ, Sch Mat Sci & Engn, Hangzhou 310018, Peoples R China; 6.Wuhan Univ Sci & Technol, State Key Lab Refractories & Met, Wuhan 430081, Peoples R China; 7.Univ Edinburgh, Sch Engn, Edinburgh EH9 3BF, Scotland; 8.Hokkaido Univ, Grad Sch Chem Sci & Engn, Sapporo 0600814, Japan; 9.Tianjin Univ, Sch Mat Sci & Engn, TJU NIMS Int Collaborat Lab, Tianjin 300072, Peoples R China |
| First Author Affilication | Coll Mat Sci & Engn |
| First Signature Affilication | Coll Mat Sci & Engn |
| Recommended Citation GB/T 7714 | Zhang, Yiming,Wang, Xusheng,Ren, Xiaohui,et al. Building rapid charge transfer channel via engineering Ni coordinated flexible polymer for efficient solar hydrogen evolution[J]. CHEMICAL ENGINEERING JOURNAL,2023,456. |
| APA | Zhang, Yiming.,Wang, Xusheng.,Ren, Xiaohui.,Luo, Shunqin.,Huang, Hengming.,...&Ye, Jinhua.(2023).Building rapid charge transfer channel via engineering Ni coordinated flexible polymer for efficient solar hydrogen evolution.CHEMICAL ENGINEERING JOURNAL,456. |
| MLA | Zhang, Yiming,et al."Building rapid charge transfer channel via engineering Ni coordinated flexible polymer for efficient solar hydrogen evolution".CHEMICAL ENGINEERING JOURNAL 456(2023). |
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