Effect of Surface Hydroxyl Content of Support on the Activity of Cu/ZSM-5 Catalyst for Low-Temperature Hydrogenation of Dimethyl Oxalate to Ethylene Glycol | |
Yun, Hongfei1; Zhao, Yu1,2; Kan, Xian1; Li, Guixian1,2 | |
2023-02 | |
发表期刊 | CATALYSIS LETTERS |
ISSN | 1011-372X |
卷号 | 153期号:2页码:364-377 |
摘要 | Cu/SiO2 catalyst prepared by the ammonia-evaporation (AE) method is the potential preferred catalyst for hydrogenation of dimethyl oxalate (DMO) to ethylene glycol (EG). Although significant advancements have been obtained in the confirmation and influence factors of active species in the hydrogenation process, the relationship between the catalytic activity and the sensitive factors in the preparation or pretreatment process of the catalyst is still uncertain. In this paper, Cu/ZSM-5 catalysts for DMO hydrogenation to EG were prepared by the AE method using ZSM-5 molecular sieve with high silicon-alumina ratio (1500) as a support. The ZSM-5 support was pretreated by drying at 393 K for different hours and it was found that the surface hydroxyl group of the support had significant influence on the structure and catalytic hydrogenation performance of the prepared Cu/ZSM-5 catalyst. The distribution of surface hydroxyl groups could be significantly changed by pre-drying the carrier, which further resulted in the change of the copper dispersion and surface properties of subsequent copper-supported catalysts. With the decrease of hydroxyl content on the surface of the ZSM-5 support, the prepared reduced Cu/ZSM-5 catalyst possessed smaller Cu-0 particles size, higher copper dispersion, higher surface area of Cu-0 and Cu+ species, but weakened surface acidity of the catalyst, which resulted in the great improvement of the catalytic activity. The DMO conversion and EG selectivity could reach 100% and 93% even under the low reaction temperature at 448 K over the Cu/ZSM-5-24 catalyst (based on the ZSM-5 support pretreated by drying for 24 h). In addition, the catalytic activity did not show obvious change after 300 h of reaction, probably due to the low temperature reaction and suitable surface properties of the catalyst. [GRAPHICS] . |
关键词 | Surface hydroxyl group Cu/ZSM-5 catalyst Dimethyl oxalate Hydrogenation Ethylene glycol |
DOI | 10.1007/s10562-022-03980-x |
收录类别 | SCIE ; EI |
语种 | 英语 |
WOS研究方向 | Chemistry |
WOS类目 | Chemistry, Physical |
WOS记录号 | WOS:000772742400001 |
出版者 | SPRINGER |
EI入藏号 | 20221411915215 |
EI主题词 | Ethylene glycol |
EI分类号 | 544.1 Copper641.1 Thermodynamics802.2 Chemical Reactions803 Chemical Agents and Basic Industrial Chemicals804 Chemical Products Generally804.1 Organic Compounds804.2 Inorganic Compounds931.2 Physical Properties of Gases, Liquids and Solids951 Materials Science |
来源库 | WOS |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | https://ir.lut.edu.cn/handle/2XXMBERH/158096 |
专题 | 石油化工学院 |
通讯作者 | Zhao, Yu; Li, Guixian |
作者单位 | 1.Lanzhou Univ Technol, Sch Petrochem Engn, Lanzhou 730050, Gansu, Peoples R China; 2.Lanzhou Univ Technol, Key Lab Low Carbon Energy & Chem Engn Gansu Prov, Lanzhou 730050, Gansu, Peoples R China |
第一作者单位 | 兰州理工大学 |
通讯作者单位 | 兰州理工大学 |
第一作者的第一单位 | 兰州理工大学 |
推荐引用方式 GB/T 7714 | Yun, Hongfei,Zhao, Yu,Kan, Xian,et al. Effect of Surface Hydroxyl Content of Support on the Activity of Cu/ZSM-5 Catalyst for Low-Temperature Hydrogenation of Dimethyl Oxalate to Ethylene Glycol[J]. CATALYSIS LETTERS,2023,153(2):364-377. |
APA | Yun, Hongfei,Zhao, Yu,Kan, Xian,&Li, Guixian.(2023).Effect of Surface Hydroxyl Content of Support on the Activity of Cu/ZSM-5 Catalyst for Low-Temperature Hydrogenation of Dimethyl Oxalate to Ethylene Glycol.CATALYSIS LETTERS,153(2),364-377. |
MLA | Yun, Hongfei,et al."Effect of Surface Hydroxyl Content of Support on the Activity of Cu/ZSM-5 Catalyst for Low-Temperature Hydrogenation of Dimethyl Oxalate to Ethylene Glycol".CATALYSIS LETTERS 153.2(2023):364-377. |
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