Electrospinning Preparation of Fe3O4/Porous Carbon Nanofibres for use as Supercapacitor Electrode Materials | |
Jiang, Xia1,2; Shi, Gaofeng1; Wang, Guoying1; Mishra, Puranjan3; Wang, Zhao1; Zhang, Qi1; Zhang, Hongquan1; Niu, Xiuli4 | |
2020-05 | |
发表期刊 | INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE |
ISSN | 1452-3981 |
卷号 | 15期号:5页码:4602-4618 |
摘要 | Fe3O4/porous carbon nanofibre (Fe3O4/CNF) was prepared by carbonization of electrospun polyacrylonitrile (PAN)/polymethylmethacrylate (PMMA) composite nanofibres and used as electrode materials for supercapacitors. The introduction of PMMA as a pore- forming agent in PAN results in an optimum pore distribution and a more suitable specific surface area for Fe3O4/CNF; the improved pores and surface area contribute to the diffusion of the electrolyte from the surface to the inside of the electrode material. Electrochemical measurements of the Fe3O4/CNF in three- and two- electrode systems reveal a maximum specific capacitance of 540 F g(-1) in the three-electrode system and a capacitance retention of 76.3 % after 5000 continuous cycles in the two-electrode system. Due to the synergistic effect of redox pseudocapacitance behaviour and bilayer capacitance, the excellent electrochemical performance of the Fe3O4/CNF electrode highlights the importance of adding PMMA into composite materials. |
关键词 | iron oxide carbon nanofibers pore structure liquefied carbon supercapacitors |
DOI | 10.20964/2020.05.72 |
收录类别 | SCIE |
语种 | 英语 |
WOS研究方向 | Electrochemistry |
WOS类目 | Electrochemistry |
WOS记录号 | WOS:000532357500075 |
出版者 | ESG |
来源库 | WOS |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | https://ir.lut.edu.cn/handle/2XXMBERH/155198 |
专题 | 石油化工学院 法学院 |
通讯作者 | Shi, Gaofeng; Wang, Guoying; Niu, Xiuli |
作者单位 | 1.Lanzhou Univ Technol, Sch Petrochem Engn, Lanzhou, Peoples R China; 2.Gansu Vocat Coll Agr, Lanzhou, Peoples R China; 3.Univ Malaysia Pahang, Fac Engn Technol, Lebuhraya Tun Razak, Kuantan 26300, Pahang, Malaysia; 4.Gansu Prov Food Inspect Inst, Lanzhou, Peoples R China |
第一作者单位 | 兰州理工大学 |
通讯作者单位 | 兰州理工大学 |
第一作者的第一单位 | 兰州理工大学 |
推荐引用方式 GB/T 7714 | Jiang, Xia,Shi, Gaofeng,Wang, Guoying,et al. Electrospinning Preparation of Fe3O4/Porous Carbon Nanofibres for use as Supercapacitor Electrode Materials[J]. INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE,2020,15(5):4602-4618. |
APA | Jiang, Xia.,Shi, Gaofeng.,Wang, Guoying.,Mishra, Puranjan.,Wang, Zhao.,...&Niu, Xiuli.(2020).Electrospinning Preparation of Fe3O4/Porous Carbon Nanofibres for use as Supercapacitor Electrode Materials.INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE,15(5),4602-4618. |
MLA | Jiang, Xia,et al."Electrospinning Preparation of Fe3O4/Porous Carbon Nanofibres for use as Supercapacitor Electrode Materials".INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE 15.5(2020):4602-4618. |
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