Defective N/S-Codoped 3D Cheese-Like Porous Carbon Nanomaterial toward Efficient Oxygen Reduction and Zn–Air Batteries

doi:10.1002/smll.201800563

	Defective N/S-Codoped 3D Cheese-Like Porous Carbon Nanomaterial toward Efficient Oxygen Reduction and Zn–Air Batteries
	Zhu, Jiawei 1; Li, Wenqiang 1; Li, Shuaihu 2; Zhang, Jian 1,3; Zhou, Huang 1; Zhang, Chengtian 1; Zhang, Jianan 4; Mu, Shichun 1
	2018-05-24
发表期刊	Small
ISSN	16136810
卷号	14 期号:21
摘要	Developing a facile and cost-efficient method to synthesize carbon-based nanomaterials possessing excellent structural and functional properties has become one of the most attractive topics in energy conversion and storage fields. In this study, density functional theory calculation results reveal the origin of high oxygen reduction reaction (ORR) activity predominantly derived from the synergistic effect of intrinsic defects and heteroatom dopants (e.g., N, S) that modulate the bandgap and charge density distribution of carbon matrix. Under the guidance of the first-principle prediction, by using ultralight biomass waste as precursor of C, N, and S elements, a defect-rich and N/S dual-doped cheese-like porous carbon nanomaterial is successfully designed and constructed. Herein, the intrinsic defects are artfully generated in terms of alkaline and ammonia activation. The electrochemical measurements display that such a material owns a comparable ORR activity (E1/2 = 0.835 V) to the commercial Pt/C catalyst, along with splendid durability and methanol tolerance in alkali media. Furthermore, as cathode catalyst, it displays a high Zn–air battery performance. The excellent ORR activity of the catalyst can be attributed to its unique 3D porous architecture, abundant intrinsic defects, and high-content active heteroatom dopants in the carbon matrix. © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
关键词	Ammonia Carbon Catalyst activity Defects Density functional theory Electrolytic reduction Energy conversion Nanostructured materials Oxygen Porous materials Charge density distributions DFT calculation Electrochemical measurements Energy conversion and storages Functional properties Oxygen reduction reaction Porous architectures Porous carbons
DOI	10.1002/smll.201800563
收录类别	EI ; SCIE
语种	英语
资助项目	Excellent Dissertation Cultivation Foundation of Wuhan University of Technology[2017-YS-013]
WOS研究方向	Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics
WOS类目	Chemistry, Multidisciplinary ; Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied ; Physics, Condensed Matter
WOS记录号	WOS:000434173300023
出版者	Wiley-VCH Verlag
EI入藏号	20182005202643
EI主题词	Zinc air batteries
EI分类号	525.5 Energy Conversion Issues - 533.1 Ore Treatment - 761 Nanotechnology - 804 Chemical Products Generally - 804.2 Inorganic Compounds - 822.1 Food Products Plants and Equipment - 922.1 Probability Theory - 951 Materials Science
来源库	Compendex
分类代码	525.5 Energy Conversion Issues - 533.1 Ore Treatment - 761 Nanotechnology - 804 Chemical Products Generally - 804.2 Inorganic Compounds - 922.1 Probability Theory - 951 Materials Science
引用统计	被引频次：135[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	https://ir.lut.edu.cn/handle/2XXMBERH/114909
专题	兰州理工大学
通讯作者	Zhang, Jian; Mu, Shichun
作者单位	1.Wuhan Univ Technol, State Key Lab Adv Technol Mat Synth & Proc, Wuhan 430070, Hubei, Peoples R China; 2.Lanzhou Univ Technol, Sch Sci, Lanzhou 730050, Gansu, Peoples R China; 3.Huazhong Univ Sci & Technol, Sch Mat Sci & Engn, State Key Lab Mat Proc & Die & Mould Technol, Wuhan 430074, Hubei, Peoples R China; 4.Zhengzhou Univ, Coll Mat Sci & Engn, Zhengzhou 450001, Henan, Peoples R China
推荐引用方式 GB/T 7714	Zhu, Jiawei,Li, Wenqiang,Li, Shuaihu,et al. Defective N/S-Codoped 3D Cheese-Like Porous Carbon Nanomaterial toward Efficient Oxygen Reduction and Zn–Air Batteries[J]. Small,2018,14(21).
APA	Zhu, Jiawei.,Li, Wenqiang.,Li, Shuaihu.,Zhang, Jian.,Zhou, Huang.,...&Mu, Shichun.(2018).Defective N/S-Codoped 3D Cheese-Like Porous Carbon Nanomaterial toward Efficient Oxygen Reduction and Zn–Air Batteries.Small,14(21).
MLA	Zhu, Jiawei,et al."Defective N/S-Codoped 3D Cheese-Like Porous Carbon Nanomaterial toward Efficient Oxygen Reduction and Zn–Air Batteries".Small 14.21(2018).