Biomass-derived porous carbons with tailored graphitization degree and pore size distribution for supercapacitors with ultra-high rate capability
He, Jingjing; Zhang, Deyi; Wang, Yulin; Zhang, Jiwei; Yang, Binbin; Shi, Hao; Wang, Kunjie; Wang, Yi
2020-06-15
发表期刊APPLIED SURFACE SCIENCE
ISSN0169-4332
卷号515
摘要

It is extraordinarily valuable to develop the supercapacitor with high capacitance retention under ultra-high current density to meet the requirement of fast charging. Herein, porous carbons with tailored graphitization degree and pore size distribution are facilely prepared via controlling the activation temperature of biomass-derived pyrolytic carbon when employing potassium ferrate (K2FeO4) as catalyst and activation agent. The obtained semi-graphitized microporous carbon with a large specific surface area (2208 m(2) g(-1)), high proportion of large micropores (more than 71.8%) and high conductivity (2.38 S cm(-1)) exhibits a perfect balance between the charge storage capacity and rate capability, which specific capacitance reaches 254 and 273 F g(-1) at a current density of 0.5 A g(-1) in KOH and H2SO4 aqueous electrolyte, respectively. Surprising capacitance retention of 86.9% is obtained under an ultra-large current density of 100 A g(-1) for the symmetrical supercapacitor based on the semi-graphitized microporous carbon, and no apparent attenuation was observed after 10,000 cycles. Furthermore, energy density of the assembled symmetrical supercapacitor reaches 7.4 Wh kg(-1) at a power density of 151.4 W kg(-1), and more than 87.8% of energy density is kept even under an ultra-large power density of 29.1 kW kg(-1).

关键词Porous carbons Tailored graphitization degree Supercapacitor Rate capability
DOI10.1016/j.apsusc.2020.146020
收录类别SCI ; SCIE ; EI
语种英语
资助项目National Natural Science Foundation of China[51462020][21867015]
WOS研究方向Chemistry ; Materials Science ; Physics
WOS类目Chemistry, Physical ; Materials Science, Coatings & Films ; Physics, Applied ; Physics, Condensed Matter
WOS记录号WOS:000525637300016
出版者ELSEVIER
EI入藏号20201108284355
EI主题词Pore size
EI分类号701.1 Electricity: Basic Concepts and Phenomena - 702 Electric Batteries and Fuel Cells - 802.2 Chemical Reactions - 803 Chemical Agents and Basic Industrial Chemicals - 804 Chemical Products Generally - 804.2 Inorganic Compounds - 922.2 Mathematical Statistics - 931.2 Physical Properties of Gases, Liquids and Solids - 951 Materials Science
来源库WOS
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被引频次:98[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符https://ir.lut.edu.cn/handle/2XXMBERH/64312
专题石油化工学院
通讯作者Zhang, Deyi
作者单位Lanzhou Univ Technol, Coll Petrochem Technol, Lanzhou 730050, Peoples R China
第一作者单位石油化工学院
通讯作者单位石油化工学院
第一作者的第一单位石油化工学院
推荐引用方式
GB/T 7714
He, Jingjing,Zhang, Deyi,Wang, Yulin,et al. Biomass-derived porous carbons with tailored graphitization degree and pore size distribution for supercapacitors with ultra-high rate capability[J]. APPLIED SURFACE SCIENCE,2020,515.
APA He, Jingjing.,Zhang, Deyi.,Wang, Yulin.,Zhang, Jiwei.,Yang, Binbin.,...&Wang, Yi.(2020).Biomass-derived porous carbons with tailored graphitization degree and pore size distribution for supercapacitors with ultra-high rate capability.APPLIED SURFACE SCIENCE,515.
MLA He, Jingjing,et al."Biomass-derived porous carbons with tailored graphitization degree and pore size distribution for supercapacitors with ultra-high rate capability".APPLIED SURFACE SCIENCE 515(2020).
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