Three-Dimensional Interconnected Microporous Carbon Network Derived from Aniline Formaldehyde Resin/Sodium Polyacrylate Interpenetrating Polymer Networks (AF/PAAS IPNs) with Controllable Porosity for Supercapacitors

doi:10.1021/acsaem.9b01044

	Three-Dimensional Interconnected Microporous Carbon Network Derived from Aniline Formaldehyde Resin/Sodium Polyacrylate Interpenetrating Polymer Networks (AF/PAAS IPNs) with Controllable Porosity for Supercapacitors
	Ma, Yan-Dong 1; Chen, Xi-Wen 1; Kong, Ling-Bin1,2
	2019-09
发表期刊	ACS APPLIED ENERGY MATERIALS
ISSN	2574-0962
卷号	2 期号:9 页码:6440-6452
摘要	A facile strategy for the synthesis of three-dimensional nitrogen-doped microporous carbon (MC-IPNx) is reported here. We adopt the advantages of cross-linking individually of interpenetrating polymer networks to synthesize porous carbon with well-controlled micropores (similar to 0.6 nm) and interconnected pores by one-step carbonization of aniline formaldehyde resin/sodium polyacrylate interpenetrating polymer networks (AF/PAAS IPNs), a radically different approach that allows AF/PAAS IPNs to be directly converted to nitrogen-doped microporous carbon (MC-IPNx) without any pretreatment. Due to the interpenetrating pores and abundant porosity, MC-IPNx acquired a high specific surface area (1275 m(2) g(-1)), which reveals remarkable specific capacity (223 F g(-1) at a current density of 1 A g(-1)) and superb capacity retention (80% retention in a current density within the range 0.5-10 A g(-1)). The unique pore structure of MC-IPNx provides an innovative idea for the control of pore size, and advanced electrochemical performance indicates its application prospects.
关键词	interpenetrating polymer networks microporous carbon controllable pore size supercapacitors electrochemical performance
DOI	10.1021/acsaem.9b01044
收录类别	SCI ; SCIE
语种	英语
资助项目	National Natural Science Foundation of China[51762031] ; Foundation for Innovation Groups of Basic Research in Gansu Province[1606RJIA322]
WOS研究方向	Chemistry ; Energy & Fuels ; Materials Science
WOS类目	Chemistry, Physical ; Energy & Fuels ; Materials Science, Multidisciplinary
WOS记录号	WOS:000487770000038
出版者	AMER CHEMICAL SOC
EI入藏号	20193707419098
EI主题词	Interpenetrating polymer networks
EI分类号	802.2 Chemical Reactions - 804 Chemical Products Generally - 804.1 Organic Compounds - 815.1 Polymeric Materials - 815.1.1 Organic Polymers - 931.2 Physical Properties of Gases, Liquids and Solids
引用统计	被引频次：7[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	https://ir.lut.edu.cn/handle/2XXMBERH/64272
专题	省部共建有色金属先进加工与再利用国家重点实验室材料科学与工程学院
通讯作者	Kong, Ling-Bin
作者单位	1.Lanzhou Univ Technol, State Key Lab Adv Proc & Recycling Nonferrous Met, Lanzhou 730050, Gansu, Peoples R China; 2.Lanzhou Univ Technol, Sch Mat Sci & Engn, Lanzhou 730050, Gansu, Peoples R China
第一作者单位	省部共建有色金属先进加工与再利用国家重点实验室
通讯作者单位	省部共建有色金属先进加工与再利用国家重点实验室; 材料科学与工程学院
第一作者的第一单位	省部共建有色金属先进加工与再利用国家重点实验室
推荐引用方式 GB/T 7714	Ma, Yan-Dong,Chen, Xi-Wen,Kong, Ling-Bin. Three-Dimensional Interconnected Microporous Carbon Network Derived from Aniline Formaldehyde Resin/Sodium Polyacrylate Interpenetrating Polymer Networks (AF/PAAS IPNs) with Controllable Porosity for Supercapacitors[J]. ACS APPLIED ENERGY MATERIALS,2019,2(9):6440-6452.
APA	Ma, Yan-Dong,Chen, Xi-Wen,&Kong, Ling-Bin.(2019).Three-Dimensional Interconnected Microporous Carbon Network Derived from Aniline Formaldehyde Resin/Sodium Polyacrylate Interpenetrating Polymer Networks (AF/PAAS IPNs) with Controllable Porosity for Supercapacitors.ACS APPLIED ENERGY MATERIALS,2(9),6440-6452.
MLA	Ma, Yan-Dong,et al."Three-Dimensional Interconnected Microporous Carbon Network Derived from Aniline Formaldehyde Resin/Sodium Polyacrylate Interpenetrating Polymer Networks (AF/PAAS IPNs) with Controllable Porosity for Supercapacitors".ACS APPLIED ENERGY MATERIALS 2.9(2019):6440-6452.