Thermophysical properties of three-dimensional palygorskite based composite phase change materials

doi:10.1016/j.clay.2019.105367

	Thermophysical properties of three-dimensional palygorskite based composite phase change materials
	Wang, Yi1,2 ; Song, Yanhui 1; Li, Shuang 1; Zhang, Ting1 ; Zhang, Deyi1,2 ; Guo, Pengran 3
	2020-01
发表期刊	APPLIED CLAY SCIENCE
ISSN	0169-1317
卷号	184
摘要	In order to enhance the loading capacity of palygorskite (Pal) and further understand the relationship between pore size of carrier and thermal properties of mineral-based phase change materials (PCMs), series of three-dimensional palygorskite carriers and corresponding composite PCMs (CPCMs) were fabricated. The morphology, structural characteristics and thermal properties of the support and composite PCMs were determined by various techniques. The effects of support microstructure on the thermo physical properties of CPCMs were also discussed. The results revealed that the isocyanate functionalized palygorskite can be covalently bonded by dihydric alcohol to form three-dimensional Pal-based carrier. The pore diameter of the carrier varies with the chain length of dihydric alcohol. Since covalent bonding and surface functionalization can prevent the agglomeration of palygorskite crystals, thermal energy storage performance of stearic acid/three-dimensional palygorskite is increased by 67.4% to 100.7% within the scope of the study compared with that of stearic acid/palygorskite. The phase change temperature and latent heat of the composite phase change material have a linear correlation with pore size of support. This study is expected to be helpful for designing mineral-based porous carrier and providing guidance for optimizing CPCMs.
关键词	Thermal energy storage Functionalized palygorskite Pore size Structure-property relationship
DOI	10.1016/j.clay.2019.105367
收录类别	SCI ; SCIE
语种	英语
资助项目	National Natural Science Foundation of China[51562023] ; Research Fund Program of Guangdong Provincial Key Laboratory of Emergency Test for Dangerous Chemicals[KF2018001]
WOS研究方向	Chemistry ; Materials Science ; Mineralogy
WOS类目	Chemistry, Physical ; Materials Science, Multidisciplinary ; Mineralogy
WOS记录号	WOS:000510399100004
出版者	ELSEVIER
EI入藏号	20194807763907
EI主题词	Phase change materials
EI分类号	641.1 Thermodynamics - 804.1 Organic Compounds - 951 Materials Science
来源库	WOS
引用统计	被引频次：21[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	https://ir.lut.edu.cn/handle/2XXMBERH/64167
专题	省部共建有色金属先进加工与再利用国家重点实验室石油化工学院
通讯作者	Wang, Yi; Guo, Pengran
作者单位	1.Lanzhou Univ Technol, Coll Petrochem Technol, Lanzhou 730050, Peoples R China; 2.Lanzhou Univ Technol, State Key Lab Adv Proc & Recycling Nonferrous Met, Lanzhou 730050, Peoples R China; 3.Guangdong Inst Anal, Guangdong Engn Technol Res Ctr On Line Monitoring, Guangdong Prov Key Lab Emergency Test Dangerous C, Guangzhou 510070, Peoples R China
第一作者单位	石油化工学院; 省部共建有色金属先进加工与再利用国家重点实验室
通讯作者单位	石油化工学院; 省部共建有色金属先进加工与再利用国家重点实验室
第一作者的第一单位	石油化工学院
推荐引用方式 GB/T 7714	Wang, Yi,Song, Yanhui,Li, Shuang,et al. Thermophysical properties of three-dimensional palygorskite based composite phase change materials[J]. APPLIED CLAY SCIENCE,2020,184.
APA	Wang, Yi,Song, Yanhui,Li, Shuang,Zhang, Ting,Zhang, Deyi,&Guo, Pengran.(2020).Thermophysical properties of three-dimensional palygorskite based composite phase change materials.APPLIED CLAY SCIENCE,184.
MLA	Wang, Yi,et al."Thermophysical properties of three-dimensional palygorskite based composite phase change materials".APPLIED CLAY SCIENCE 184(2020).