Thermodynamic analysis of Ti powder synthesized by SHS thermitreaction
Zhang Peng-lin1,2; Xia Tian-dong1,2; Zhang Guo-dong3; Yan Li-jing2; Zhao Wen-jun1
2007-11
发表期刊TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA
ISSN1003-6326
卷号17页码:S27-S31
摘要According to the thermodynamics theories, the reactive Gibbs free energies, the reactive adiabatic temperature, the melting rate of Ti and the gasification mass of Mg in the Mg-TiO2 and Al-TiO2 systems were theoretically calculated and analyzed respectively. The results show that the reactions of Mg-TiO2 and Al-TiO2 are very easy to take place and the reaction of producing various suboxides of Ti may occur in Mg-TiO2 and Al-TiO2 reaction system; the adiabatic temperature of Mg-TiO2 becomes lower with increasing mass fraction of Mg. The adiabatic temperature is below 1 800 K when the mass fraction of excessive Mg exceeds 25%; The adiabatic temperature of Al-TiO2 also becomes lower with increasing mass fraction of Al, but it becomes higher with the preheat temperature increment. The adiabatic temperature plateau is the result of Ti melting endotherm; owing to the gasification of a great deal of Mg in Mg-TiO2 reaction process, Mg should be properly excessive in order to get Ti.
关键词self-propagating high-temperature synthesis(SHS) thermodynamic analysis adiabatic temperature Mg-TiO2 Al-TiO2
收录类别SCI ; SCIE ; CPCI
语种英语
WOS研究方向Metallurgy & Metallurgical Engineering
WOS类目Metallurgy & Metallurgical Engineering
WOS记录号WOS:000251737200007
出版者ELSEVIER SCIENCE BV
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被引频次[WOS]:0   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符https://ir.lut.edu.cn/handle/2XXMBERH/35571
专题材料科学与工程学院
通讯作者Zhang Peng-lin
作者单位1.Lanzhou Univ Technol, State Key Lab Gansu Adv Nonferrous Metal Mat, Lanzhou 730050, Peoples R China
2.Lanzhou Univ Technol, Key Lab Non Ferrous Metal Alloy, Lanzhou 730050, Peoples R China
3.Wuhan Univ, Coll Power & Mech Engn, Wuhan 430072, Peoples R China
第一作者单位兰州理工大学
通讯作者单位兰州理工大学
第一作者的第一单位兰州理工大学
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GB/T 7714
Zhang Peng-lin,Xia Tian-dong,Zhang Guo-dong,et al. Thermodynamic analysis of Ti powder synthesized by SHS thermitreaction[J]. TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA,2007,17:S27-S31.
APA Zhang Peng-lin,Xia Tian-dong,Zhang Guo-dong,Yan Li-jing,&Zhao Wen-jun.(2007).Thermodynamic analysis of Ti powder synthesized by SHS thermitreaction.TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA,17,S27-S31.
MLA Zhang Peng-lin,et al."Thermodynamic analysis of Ti powder synthesized by SHS thermitreaction".TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA 17(2007):S27-S31.
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