Fabrication of Amino Functionalized Magnetic Expanded Graphite Nanohybrids for Application in Removal of Ag(I) from Aqueous Solution
Ma, Ying-Xia; Ruan, Yong-Xin; Xing, Dan; Du, Xue-Yan; La, Pei-Qing
2017
发表期刊JOURNAL OF NANOMATERIALS
ISSN1687-4110
卷号2017
摘要Ethylenediamine functionalized magnetic expanded graphite decorated with Fe3O4 nanoparticles (MEG-NH2) was fabricated by one-pot solvothermal method. The as-prepared MEG-NH2 nanohybrids were characterized by means of scanning electron microscopy (SEM), X-ray diffraction (XRD), Fourier transform infrared spectra (FTIR), X-ray photoelectron spectroscopy (XPS), thermogravimetric analysis (TGA), vibrating sample magnetometer (VSM), and Zeta potential analyzer. The effects of Fe3O4 content in MEG-NH2 nanohybrids, pH, initial concentration, contact time, and dosage on adsorption properties of the MEG-NH2 nanohybrids for Ag(I) from aqueous solution were investigated by batch experiments. The pseudo-first-order and the pseudosecond-order kinetic models were utilized to study adsorption kinetics. The experimental data was also analyzed with Langmuir, Freundlich, Temkin, and Dubinin-Radushkevich isothermmodels. The results show that Ag(I) was reduced to silver in the process of the adsorption by MEG-NH2 nanohybrids; the experimental data was better fitted to pseudo-second-order model and Langmuir isotherm model which revealed that the adsorption process was a chemical adsorption by the formation of silver on the surface of MEG-NH 2 nanohybrids.
关键词Ethylene glycol Fabrication Fourier transform infrared spectroscopy Graphite Iron oxides Isotherms Magnetite Nanomagnetics Nanostructured materials Photoelectron spectroscopy Scanning electron microscopy Silver compounds Thermogravimetric analysis X ray photoelectron spectroscopy
DOI10.1155/2017/6839474
收录类别SCI ; SCIE
语种英语
资助项目National Natural Science Foundation of China[51403091] ; Postdoctoral Science Foundation of China[2015M572616]
WOS研究方向Science & Technology - Other Topics ; Materials Science
WOS类目Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary
WOS记录号WOS:000394856500001
出版者HINDAWI LTD
EI入藏号20170803377606
EI主题词Adsorption
EI分类号701.2 Magnetism: Basic Concepts and Phenomena - 761 Nanotechnology - 801 Chemistry - 802.3 Chemical Operations - 804.1 Organic Compounds - 804.2 Inorganic Compounds
引用统计
被引频次:9[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符https://ir.lut.edu.cn/handle/2XXMBERH/33430
专题研究生院
材料科学与工程学院
通讯作者Ma, Ying-Xia; Du, Xue-Yan
作者单位Lanzhou Univ Technol, Key Lab Nonferrous Met Alloys & Proc, Minist Educ,Sch Mat Sci & Engn, State Key Lab Adv Proc & Recycling Nonferrous Met, Lanzhou 730050, Peoples R China
第一作者单位兰州理工大学
通讯作者单位兰州理工大学
第一作者的第一单位兰州理工大学
推荐引用方式
GB/T 7714
Ma, Ying-Xia,Ruan, Yong-Xin,Xing, Dan,et al. Fabrication of Amino Functionalized Magnetic Expanded Graphite Nanohybrids for Application in Removal of Ag(I) from Aqueous Solution[J]. JOURNAL OF NANOMATERIALS,2017,2017.
APA Ma, Ying-Xia,Ruan, Yong-Xin,Xing, Dan,Du, Xue-Yan,&La, Pei-Qing.(2017).Fabrication of Amino Functionalized Magnetic Expanded Graphite Nanohybrids for Application in Removal of Ag(I) from Aqueous Solution.JOURNAL OF NANOMATERIALS,2017.
MLA Ma, Ying-Xia,et al."Fabrication of Amino Functionalized Magnetic Expanded Graphite Nanohybrids for Application in Removal of Ag(I) from Aqueous Solution".JOURNAL OF NANOMATERIALS 2017(2017).
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