Spectroscopic properties of a chromone-fluorescein conjugate as Mg2+ "turn on" fluorescent probe
Li, Chao-rui1; Li, Si-liang1,2; Wang, Guan-qun1; Yang, Zheng-yin1
2018-04
发表期刊JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY
ISSN1010-6030
卷号356页码:700-707
摘要In this study, a novel fluorescein-derived Schiff-base ligand bearing a chromone moiety which was called 6-Hydroxy-3-formylchromone fluorescein hydrazone (1) has been designed, synthesized and evaluated as a Mg2+ "turn on" fluorescent probe. This probe 1 exhibited high selectivity and sensitivity towards Mg2+ over other important metal ions investigated, and the remarkable enhancement in fluorescence emission centered at 504 nm was observed in the presence of Mg2+, which was attributed to the ring opening process of the fluorescein fluorophore in probe 1 upon complexation of 1 with Mg2+. Furthermore, the "turn on" response of this probe 1 to Mg2+ was nearly completed within 3 min, which indicated that this probe 1 could be utilized to sense and monitor Mg2+. for real-time detection. (C) 2016 Elsevier B.V. All rights reserved.
关键词Fluorescein Fluorescent probe Magnesium ion Selectivity Sensitivity
DOI10.1016/j.jphotochem.2016.03.001
收录类别SCI ; SCIE
语种英语
资助项目Gansu NSF[1308RJZA115]
WOS研究方向Chemistry
WOS类目Chemistry, Physical
WOS记录号WOS:000428972800079
出版者ELSEVIER SCIENCE SA
引用统计
被引频次:19[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符https://ir.lut.edu.cn/handle/2XXMBERH/32719
专题石油化工学院
通讯作者Yang, Zheng-yin
作者单位1.Lanzhou Univ, State Key Lab Appl Organ Chem, Coll Chem & Chem Engn, Lanzhou 730000, Gansu, Peoples R China;
2.Lanzhou Univ Technol, Sch Petrochem Engn, Lanzhou 730050, Gansu, Peoples R China
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Li, Chao-rui,Li, Si-liang,Wang, Guan-qun,et al. Spectroscopic properties of a chromone-fluorescein conjugate as Mg2+ "turn on" fluorescent probe[J]. JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY,2018,356:700-707.
APA Li, Chao-rui,Li, Si-liang,Wang, Guan-qun,&Yang, Zheng-yin.(2018).Spectroscopic properties of a chromone-fluorescein conjugate as Mg2+ "turn on" fluorescent probe.JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY,356,700-707.
MLA Li, Chao-rui,et al."Spectroscopic properties of a chromone-fluorescein conjugate as Mg2+ "turn on" fluorescent probe".JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY 356(2018):700-707.
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