Enhance supercapacitive performance of MnO2/3D carbon nanotubes-graphene as a binder-free electrode
Bi, Tiantian1,2; Fang, Huaqing2; Jiang, Jinlong1,2; He, Xingxing2; Zhen, Xuan2; Yang, Hua2; Wei, Zhiqiang2; Jia, Zhengfeng3
2019-05-30
发表期刊JOURNAL OF ALLOYS AND COMPOUNDS
ISSN0925-8388
卷号787页码:759-766
摘要In this paper, the MnO2/three-dimensional carbon nanotubes-graphene nanocomposite was synthesized on Cu foil substrate by chemical vapor deposition and subsequent thermal decomposition of manganese acetyllacetonate precursors. The nanocomposite material was directly used as a binder-free electrode to investigate the supercapacitive performance. The results indicate that the appropriate defects and MnO2 nanoparticles are introduced simultaneously into the carbon nanotubes-graphene architecture in one-step. The specific capacitance of MnO2/three-dimensional carbon nanotubes-graphene/Cu electrode is up to 365 F g(-1) at a current density of 1 A g(-1) in 1.0 M Na2SO4 solution, which is 9 times higher than that of electrode without MnO2 modification. After 1000 cycles at 1 A g(-1), the capacity retention is still maintained at 97.0%, suggesting potential applications in high-performance energy storage devices. The excellent electrochemical performances of nanocomposite electrode can be attributed to the significantly synergistic effects between the lasting electronic conductivity of three-dimensional carbon nanotubes-graphene/Cu with the appropriate defects and the pseudocapacitance of the MnO2 nanoparticles. (C) 2019 Elsevier B.V. All rights reserved.
关键词3D carbon nanotubes-graphene Manganese oxide Thermal decomposition Supercapacitor
DOI10.1016/j.jallcom.2019.02.117
收录类别SCI ; SCIE
语种英语
资助项目National Natural Science Foundation of China[51741104]
WOS研究方向Chemistry ; Materials Science ; Metallurgy & Metallurgical Engineering
WOS类目Chemistry, Physical ; Materials Science, Multidisciplinary ; Metallurgy & Metallurgical Engineering
WOS记录号WOS:000462592500087
出版者ELSEVIER SCIENCE SA
EI入藏号20190806520944
EI主题词Sulfur compounds
EI分类号701.1 Electricity: Basic Concepts and Phenomena - 761 Nanotechnology - 802.2 Chemical Reactions - 804 Chemical Products Generally - 804.2 Inorganic Compounds - 933 Solid State Physics - 951 Materials Science
引用统计
被引频次:41[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符https://ir.lut.edu.cn/handle/2XXMBERH/31854
专题省部共建有色金属先进加工与再利用国家重点实验室
理学院
通讯作者Jiang, Jinlong
作者单位1.Lanzhou Univ Technol, State Key Lab Adv Proc & Recycling Nonferrous Met, Lanzhou 730050, Gansu, Peoples R China;
2.Lanzhou Univ Technol, Dept Phys, Sch Sci, Lanzhou 730050, Gansu, Peoples R China;
3.Liaocheng Univ, Coll Mat Sci & Engn, Liaocheng 252059, Peoples R China
第一作者单位省部共建有色金属先进加工与再利用国家重点实验室;  理学院
通讯作者单位省部共建有色金属先进加工与再利用国家重点实验室;  理学院
第一作者的第一单位省部共建有色金属先进加工与再利用国家重点实验室
推荐引用方式
GB/T 7714
Bi, Tiantian,Fang, Huaqing,Jiang, Jinlong,et al. Enhance supercapacitive performance of MnO2/3D carbon nanotubes-graphene as a binder-free electrode[J]. JOURNAL OF ALLOYS AND COMPOUNDS,2019,787:759-766.
APA Bi, Tiantian.,Fang, Huaqing.,Jiang, Jinlong.,He, Xingxing.,Zhen, Xuan.,...&Jia, Zhengfeng.(2019).Enhance supercapacitive performance of MnO2/3D carbon nanotubes-graphene as a binder-free electrode.JOURNAL OF ALLOYS AND COMPOUNDS,787,759-766.
MLA Bi, Tiantian,et al."Enhance supercapacitive performance of MnO2/3D carbon nanotubes-graphene as a binder-free electrode".JOURNAL OF ALLOYS AND COMPOUNDS 787(2019):759-766.
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